Organic chemistry 2
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alcohols functional group
-OH
alcohols general formula
CnH2n+1OH
name the alchohols
• methanol • ethanol • propanol • butanol
molecular formula of methanol
CH3OH
molecular formula of ethanol
C2H5OH
structural formula of ethanol
CH3CH2OH
molecular formula of propanol
C3H7OH
structural formula of propanol
CH3CH2CH2OH
molecular formula of butanol
C4H9OH
structural formula of butanol
CH3CH2CH2CH2OH
name the 3 methods of oxidising ethanol
• complete combustion • microbial oxidation • using an oxidising agent of potassium dichromate (VI)
word equation for combustion of ethanol
ethanol + oxygen —> carbon dioxide + water
symbol equation for combustion of ethanol w/state symbols
C2H5OH (l) + 3O2 (g) —> 2CO2 (g) + 3H2O (l)
how can you confirm that the combustion reaction of ethanol has occurred?
• the 2 products are CO2 and H2O • H2O = collect liquid which makes white anhydrous copper(II) sulfate turns blue • CO2 = collect gas which makes limewater turns cloudy
what bacteria in the air causes the oxidation of ethanol to occur?
acetobacter
word equation of microbial oxidation of ethanol
ethanol + oxygen —(acetobacter)—> ethanoic acid + water
symbol equation of microbial oxidation of ethanol w/state symbols
C2H5OH (l) + O2 (g) —(acetobacter)—> CH3COOH (l) + H2O (l)
what is ethanol heated with during the oxidation of ethanol by an oxidising agent?
• sulfuric acid (creates acidic conditions for the oxidising agent to work in) • oxidising agent - potassium dichromate (VI)
word equation for the oxidation of ethanol by an oxidising agent
ethanol + oxidising agent —(sulfuric acid + heat)—> ethanoic acid + water
what are the observations of the oxidation of ethanol by an oxidising agent
• colour change from orange to green • smells like vinegar
symbol equation for the oxidation of ethanol by an oxidising agent w/state symbols
C2H5OH (l) + 2[O] -(H2SO4 (aq) and heat)—> CH3COOH (l) + H2O(l)
what are the 2 main methods of manufacture of ethanol?
• hydration of ethene with steam • fermentation of glucose
conditions for hydration of ethene with steam to form ethanol
• 60-70 atm pressure • 300°C temperature • concentrated phosphoric acid catalyst
conditions for fermentation of glucose
• 30°C optimum temperature for enzymes (biolog. catalyst) in yeast = increases RoR • absence of oxygen to force yeast to respire anaerobically to produce ethanol • if oxygen was present no ethanol would be produced as the yeast would respire aerobically and make carbon dioxide and water