4.1 Basic Concepts And Hydrocarbons
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General formula
An algebraic formula that can describe any member of a family of compounds
Empirical forumla
Simplest whole number ratio of atoms of each elemnt in a compound
Molecular formula
Actual number of atoms of each element in a molecule
Structurual forumla Like for Butan-1-ol
Shows arrangement of atom carbon by carbon, with the attached hydrogen and functional group CH3CH2CH2CH2OH or CH3(CH2)30H
Skeletal formula
Shows the bond of the carbon skeleton only, with any functional groups. The hydrogen and carbon atoms aren’t shown. (zig zag and ring ones)
Displayed forumla
Shows how all the atoms are arranged, and all the bonds between them
Branched alkanes prefix or suffix General formula for alkanes?
alkyl-(-yl) CnH2n+2
haloalkanes prefix or suffix
chloro-/bromo-/iodo-
aldehyde prefix or suffix
-al
ketones prefix or suffix General formula for ketones?
-one CnH2nO
cycloalkanes prefix or suffix General formula for cycloalakane?
cyclo-…-ane CnH2n
carboxyclic acid prefix or suffix General formula for carboxcylic acid?
-oic acid CnH2n+1COOH
ester prefix or suffix
alkyl-…-anoate
Structural isomers
Compounds with the same molecular formula but different structural formula
Homolytic fission
Breaking a covalent bond to form two radicals Where each bonding atom is receiving one electron from the bonded pair
Heterolytic fission
Breaking a covalent bond to form two oppositely charged ions where one bonding atom receives both electrons from the bonded pair
Curly Arrow
Shows the movement of an electron pair during a reaction
What are the 3 steps in free radical substitution
• initiation • propagation • termination
what is the initiation equations for methane and chlorine to give chloro-methane and hydrogen chloride
CL2 –> 2CL.
what are the 2 propagation equations for methane and chlorine to give chloro-methane and hydrogen chloride
Cl. + CH4 –> CH3. +HCl Cl2 + CH3. –>CH3Cl +Cl.
what are the termination step equations for methane and chlorine to give chloro-methane and hydrogen chloride
Cl. + Cl. –> Cl2 Cl. +CH3. –>CH3Cl CH3. + CH3 –> C2H6
Why do branch isomers have lower MP then straight chained isomers?
Can’t pack close to each other and smaller molecular surface areas so less surface contact between molecules… less induced dipole forces… so less energy to break force
Why does BP increase as chain lengths increase for hydrocarbons?
Stronger intermolecular forces
Why does adding carbon to a chain start to become less significant in terms of boiling point?
As the mass is increasing by a small percentage each time