organic synthesis 3.3.14 in papers 2 + 3
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what is the test for alkenes and what is observed?
• bromine water • orange to colourless (decolourises)
whats the test for aldehydes and what is observed?
• tollens reagent • silver mirror • fehlings solution • blue solution to brick red percipitate
what is the test for carboxylic acids and what is observed?
• sodium carbonate • effeverscene
what is the test for alcohols and aldehydes and what is observed?
• pottasium dichromate • orange to green
what is the test for haloalkenes and what is observed?
• silver nitrate • white percipitate for Cl • cream percipitate for Br • yellow percipitate for I
whats the test for acyl chlroides and what is observed?
• silver nitrate • steamy fumes of HCl + white percipitate
whats the synthesis route for an alkene to dihalogenalkane?
• Br2, Cl2 • electrophillic addition
whats the synthesis route for a dihalogenalkane to diol?
• KOH aqeuous • nucleophillic subsitution
whats the synthesis route for a halogenalkane to alkene?
• KOH alcoholic • elimination
whats the synthesis route for an alkane to halogenoalkane?
• Br2, Cl2 • UV light • free radical subsitution
whats the synthesis route for an alkene to halogenoalkane?
• HBr, HCl • electrophillic addition
whats the synthesis route for a halogenoalkane to an alcohol?
• KOH aqeuous • nucleophillic subsitution
whats the synthesis route for an alkene to an alcohol?
• H2SO4 • electrophillic addition • H2O • hydrolysis
whats the synthesis route for an alcohol to an alkene?
• conc H2SO4 • elimination / dehydration
whats the synthesis route for a halogenoalkane to a nitrile?
• KCN ethanolic • nucleophillic subsititution
whats the synthesis route for a halogenoalkane to a primary amine?
• ethanolic NH3 • nucleophillic subsitution
whats the synthesis route for a nitrile to primary amine?
• LiAl4 • reduction
whats the synthesis route for a primary amine to a secondary/tertiary amine or quaternary sub?
• halogenoalkane • nucleophillic subsitution
whats the synthesis route for a primary amine to a secondary amide?
• acyl chloride • nucelophillic addition - elimination
whats the synthesis route for an alcohol to an aldehyde or ketone?
• pottasium dichromate • oxidation
whats the synthesis route for an aldehyde or ketone to alcohol?
• NaBH4 • nucleophillic addition • reduction
whats the synthesis route for an aldehyde or ketone to a hydroxynitrile?
• KCN + H2SO4 • nucleophillic addition
whats the synthesis route for an alcohol to an ester?
• carboxylic acid + H2SO4 • esterfication
whats the synthesis route for an aldehyde to a carboxylic acid?
• pottasium dichromate • oxidation