(O) Topic 29 - Polymerisation
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What are the two main types of polymer chains?
Addition and Condensation
What are the two types of condensation polymers?
polyesters and polyamides
What is the strongest force of attraction between addition polymer chains
Van der Waals
What is the strongest force of attraction between polyester chains?
Permanent dipole dipole forces (due to polar C=O bonds)
What is the strongest force of attraction between polyamide chains
Hydrogen bonds (due to polar presence of N-H bonds within molecules)
Name an example of a polyester and its use
terylene (PET) - used in drinks bottles
Name two examples of an addition polymer and its uses
poly(ethene) - polythene bags PVC - PVC pipes in plumbing
Name two examples of a polyamide and its uses
Nylon-6,6 - Clothing Kevlar - Bullet proof vests
What is the bond between molecules in polyesters called?
An Ester Bond
What is the bond between molecules in a polyamide called?
peptide bonds
Describe and explain the biodegradability of addition polymers
Non-Biodegradable due to the absence of polar bonds, only containing C-C and C-H bonds. Nothing in the natural environment will break them down and they persist for many years.
Describe and explain the biodegradability of condensation polymers
Potentially biodegradable due to the presence of polar C-N and C-O bonds, and so can be broken down by hydrolysis. However, this process is very slow under everyday conditions.
How is a polyamide formed
Many dicarboxylic acids and diamines react together in a series of condensation reactions, releasing water
Describe how a polyester is formed
When many dihols and dicarboxyllic acid molecules react together in a series of condensation reactions, releasing water
How can addition polymers be disposed of?
Left in landfill sites or incinerated. When incinerated, CO2 and H2O are produced (which are green house gases). Toxic products may be released if not burnt properly, such as styrene, carbon monoxide and black smoke