C9 - Crude oil
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crude oil
finite resource found in rocks -formed by remains of small sea animals/plants + pressurised rock -mixture of different hydrocarbons
hydrocarbons
-compounds containing only hydrogen and carbon atoms
fractions
-before use, crude oil is split into different substances with similar boiling points
distillation
-separates substances with different boiling points
alkanes
-saturated hydrocarbons -contains max hydrogen atoms
formula for alkane
CnH(2n+2) -for every n carbon atoms there are (2n+2) H atoms
short chain molecule hydrocarbons (5)
-lower boiling point -ignite + burn better -more volatile -low viscosity = runny -higher flammability
why are short chain hydrocarbons more useful
-burn better -with cleaner, less smoky flames -useful fuels
viscosity
low = good ability to flow -the internal friction of a moving fluid
Long chain hydrocarbon properties (4)
-higher boiling point -less volatile -thick = high viscosity -lower flammability
Fractional distillation
-each hydrocarbon fraction = similar boiling point -due to diff size molecules -collected at diff levels as gas condenses
Fractional distillation - smallest molecules
-lowest boiling point -pumped from cooler top of gas -lighter fractions
Where are lighter fractions used
-combustion
products of complete combustion
-water -co2
Test for complete combustion - water
-turns blue cobalt chloride paper pink -or white anhydrous copper sulfate blue
Test for complete combustion - co2
-turns limewater cloudy
Incomplete combustion
-less oxygen -some carbon atoms form carbon monoxide instead of carbon dioxide
Carbon monoxide danger
-odourless -colourless -toxic -carried around body instead of o2
cracking
-larger, less useful hydrocarbons are broken down into smaller ones
Heavier fractions
-made from larger molecules -difficult to vaporise -do not burn easily (poor fuels)
In the cracker
-heavy fractions heated to vaporise hydrocarbons -vapour is passed over hot catalyst or -mixed w steam + heated
Cracking reaction
thermal decomposition -larger to smaller molecules
alkene product
-product made from cracking
alkene meaning
-unsaturated compounds containing at least one double bond between carbon atoms -2 fewer H atoms than alkanes