2.9 Skincare
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Exposure to UV
Can result in molecules gaining sufficient energy for bonds to be broken - responsible for sunburn and contributes to aging of skin
UVA & UVB
Cause wrinkles by breaking down collagen, creating substances called free radicals that inhibit the natural repair of the skin
Free radical
Chemical species that contains one unpaired electron and is highly reactive
Free radicals
Have unpaired electrons and are highly reactive
Initiation
UV light provides energy for the homolytic fission of halogen into reactive halogen atoms or free radicals
Propagation
Free radicals collide with other species but the number of free radicals is maintained
Termination
Free radical are used up by collision with eachother
Steps of free radical chain reactions
Initiation, propagation, termination
Evidence to support free radical chain reactions
• Reaction is initiated by UV and once started can continue in the dark • Other substitution products are made such as Ch2Br2, CHBr3, CBr4, together with longer alkanes
Free radical scavengers
Present in many cosmetic products, they contain molecules which can react with free radicals to form stable molecules and prevent chain reaction (melatonin, vitamin E)