Redox reactions
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Oxidising agent
• accepts electrons from another reagent • is reduced
Reducing agent
• gives electrons to another reagent • is oxidised
Draw an electrochemical cell
• salt bridge • high resistance voltmeter • metal electrodes • aqueous solution (1moldm^-3) • standard conditions 298K, 100KPa
Negative standard electrode potential
• produces more electrons • oxidised • stronger reducing agent • equilibrium shifts to the left
Standard electrode potential
• the potential difference of a cell • when the electrode is connected to the standard hydrogen electrode • under standard conditions
Draw the standard hydrogen electrode
Cell voltage formula
right E- left E
Affect of concentration on electrode potential
• equilibrium will shift to counteract the change • changes concentration of electrons
Feasibility of reaction
• must have positive cell potential • rate of reaction has no effect
Lithium half cell battery advantage
• low density • high reactivity • high electrode potential
Lithium half cell battery disadvantage
• toxic • fire risk- high reactivity
Fuel cell
• energy from reaction of fuel with oxyegn • fuel- hydrocarbon, hydrogen or alcohol • creates a voltage • acidic or alkaline solution
Advantage of fuel cell
• greater efficiency • only H2O formed- not polluting
Disadvantage of fuel cell
• H2 difficult to store • H2 difficult to manufacture initially
Positive standard electrode potential
• gains electrons • reduced • stronger oxidising agent • equilibrium shifts to the right
Potassium manganate titration
• manganate MnO4- is oxidising agent • reduced to Mn^2+ • Fe^2+ is reducing agent • oxidised to Fe^3+ • turns from purple to pink
Acid in KMnO4
• dilute sulfuric acid • doesnt oxidise • doesnt react with manganate ions
Iodine-thiosulfate titration
• S2O3^2- is reducing agent • oxidised to S4O6^2- • I2 is oxidising agent • reduced to I-
Iodine-thiosulfate indicator
yellow to blue-black