Acids And PH
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Acid
Proton donor
Base
Proton acceptor
Alkali
Base that’s soluble in water
Acid base general equation
HA + B —> BH+ + A- A + B —> CA + CB
Conjugate base
Base derived from acid
Conjugate acid
Acid derived from a base
Strong acid definition and example
Ions fully dissociated in water HCl —> Cl- + H+
Weak acid definition and example
Ions slightly dissociated in water CH3CO2H —>< H+ + CH3CO2 constant k indicates dissociation level
Mono/di/tri basic acid examples and dissociation trend
Mono hydrochloric HCl Di sulphuric H2SO4 Tri phosphoric H3PO4 1st dissociation strongest 3rd dissociation weakest
pH definitions and equation
H+ conc pH = -log[H+] [H+] = 10^-pH
Strong Vs weak acid trends in pH and [H+]
Strong, +pH 1, xconc 10 Weak, +pH 1, xconc 20
Mono/di/tri strength compared to [acid]
Mono = Di >/= Tri >
Kw equation and alkaline solutions
Kw = [H+] x [OH-] = 1x10^-14 298K, pure water [H+] = Kw/[OH-]
Strong acid and alkali calculations
Mol H+/OH- before mixing Find excess conc Moles/new total vol Kw, find new H+ Use pH equ
Amphoteric
Accept/donate protons simultaneously
Ka expression and simplification
([H+][A-])/[HA] [H+]^2/[acid]
Ka assumptions and their effect
Acid provides more H= than water, ignore water H+, [H+] = [A-], overestimate top Fails when [H+] is very small/close to Kw Little dissociation, most acid is HA, [acid] = [HA], overestimate bottom Fails when [H+] is very large/close to 1
Titration curve marking points
Ph vs acid/alkali volume Start pH Flattish start Vertical/equivalence volume Vertical length Final pH (never reaches 14, initial acid dilutes)
Describe the different titration curves
SS steep, steep SW steep, gentle WS gentle, steep, initial rapid WW gentle, gentle, initial rapid Di/tri protein, multiple equivalence/midpoints
Calculating Ka from a titration curve
Half equ point A- = HA A-/HA = 1 Ka = [H+] (-log = p) PKa = pH
Indicator compositions and equation
Weak acid and cb that are different colours Changes colour at equivalence point PKin = mid pH range Hin —>< in- + H+ PKin = constant Kin = ([in-][H+])/[Hin]
Methyl orange range and exclusion
3.7 Weak acid
Phenolphthalein range and exclusion
9.3 Weak base
Buffer composition ad function
Resist pH change in industrial/biochemical systems Still changes pH a bit Weak acid + cb