Aromatics (P2+P3)
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Describe the shape of Benzene
Planar hexagonal - bond angle = 120 bond lengths are equal
Describe the bonding in Benzene
each carbon bonded to 3 other atoms by covalent bonds spare electrons in P orbitals overlap to form Pi bond delocalisation of electrons
Describe the stability of Benzene
delta H hydrogenation for cyclohexatriene is -360 delta H hydrogenation for benzene is 152 less exothermic than expected benzene is more stable (less reactive)
Name the mechanism, reagents and conditions for the nitration of benzene
Electrophilic substitution reagents and conditions; conc H2SO4 and HNO3
Equation for the NO2+ electrophile being formed for the nitration of benzene?
H2SO4 + HNO3 –> HSO4- + H2O + NO2+
Name the mechanism, reagents and conditions for the acylation of benzene
Electrophilic substitution reagents and conditions; acyl chloride and AlCl3 catalyst
Equation for the RCO+ electrophile being formed for the acylation of benzene?
RCOCl + AlCl3 –> RCO+ + AlCl4-
Equation for the reformation of the catalyst for nitration of benzene
H+ + HSO4- –> H2SO4
Equation for the reformation of the catalyst for the acylation of benzene
AlCl4- + H+ –> HCl + AlCl3