CH.7 periodic table and energy
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what is periodicity
the repeating pattern in chemical and physical properties across a period
group 1
alkali metals
group 2
alkaline earth metals
group 7
halogens
group 0
noble gasses
define ionisation energy
a measure of how easily an atom looses electrons to form + ions
first ionisation energy
energy required to remove 1 mol of electrons from 1 mol of gaseous atoms
what can affect ionisation energy
atomic radius, nuclear charge, electron shielding
atomic radius
distance between outer electrons and the nucleus, larger it is the less the nuclear attraction.
nuclear charge
more protons in the nucleus the greater the attraction between the nucleus and the outer electrons.
electron sheilding
inner shell electrons repel outer shell electrons, this repulsion is the shielding effect. it reduces the attraction between the nucleus and the outer shell electrons
going down a group
atomic radius increases shielding increases nuclear attraction decreases nuclear charge increases (effect is outweighed by other factors) 1st ionisation energy decreases
going across a period
nuclear charge increases same shell so shielding similar nuclear attraction increases atomic radius decreases 1st ionisation energy increases
in periods 2 and 3 where are the dips in 1st ionisation energy
2: Be -> B 3: Mg -> Al due to a new orbital filling up 2: N -> O 3: P -> S due to electrons in an orbital pairing up and repelling each other
what is a metallic bond
the strong electrostatic attraction between cations and anions.
explain the trend in melting point across period 2 and 3
increase from Li -> C sharp decrease from C -> N (giant to simple molecular) comparatively low from N -> Ne increase from Na -> Si sharp decrease from Si -> P (giant to simple molecular) increase a bit to S decreases from S -> Ar
what elements form giant covalent structures
B, C, Si, and As