24 reaction of aqueous ions
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define hydration enthalpy
the standard enthalpy change when one mole of gaseous ions is converted to one mole of aqueous ions
when ions are hydrated what are positive ions attracted to?
slightly negative oxygen in water molecules
when ions are hydrated what are negative ions attracted to?
slightly positive hydrogens in water molecules
what is a complex ion?
central atom or ion surrounded by ligands
what is a coordinate bond?
shared pair of electrons that have both come from the same atom
define ligand
ion or molecule with a lone pair of electrons which can form a coordinate bond with a transition metal ion
define coordination number
number of coordinate bonds a transition metal ion forms
what are 4 hexa aqua complex ions?
[Cu(H2O)6]2+ [Fe(H2O)6]2+ [Fe(H2O)6]3+ [Al(H2O)6]3+
what is each hexa aqua complex ion’s colour?
[Cu(H2O)6]2+ = blue solution [Fe(H2O)6]2+ = pale green solution [Fe(H2O)6]3+ = yellow brown solution [Al(H2O)6]3+ = colourless solution
what colour is [Cu(H2O)6]2+?
blue solution
what colour is [Fe(H2O)6]2+?
pale green solution
what colour is [Fe(H2O)6]3+?
yellow brown solution
what colour is [Al(H2O)6]3+
colourless solution
which hexa aqua complex ions are more acidic?
3+ ions
why are the 3+ ions more acidic?
smaller with higher charge more polarising attracts lone pair in O weakens O-H can release H+ more easily
write an equation to show [Fe(H2O)6]3+ acting as an acid
[Fe(H2O)6]3+ -> [Fe(H2O)5(OH)]2+ + H+
what 3 things do all the hexa aqua complex ions react with?
Na2CO3 NaOH NH3
how does [Fe(H2O6)]2+ react with Na2CO3? state the observation
[Fe(H2O)6]2+ + CO3 2- -> FeCO3 (s) + 6H2O green solution -> green precipitate
how does [Fe(H2O6)]2+ react with NaOH? state the observation
[Fe(H2O6)]2+ + 2OH- -> [Fe(H2O)4(OH)2] (s)+ 2H2O green solution -> green precipitate
how does [Fe(H2O6)]2+ react with NH3? state the observation
[Fe(H2O6)]2+ + 2NH3 -> [Fe(H2O)4(OH)2] (s) + 2NH4+ green solution -> green precipitate
how does [Cu(H2O)6]2+ react with Na2CO3? state the observation
[Cu(H2O)]2+ + CO3 2- -> CuCO3 (s) + 6H2O blue solution -> blue green precipitate
how does [Cu(H2O)6]2+ react with NaOH? state the observation
[Cu(H2O)6]2+ + 2OH- -> [Cu(H2O)4(OH)2] (s) + 2H2O blue solution -> blue precipitate
how does [Cu(H2O)6]2+ react with NH3? state the observation
[Cu(H2O)6]2+ + 2NH3 -> [Cu(H2O)4(OH)2] (s) + 2NH4+ blue solution -> blue precipitate
what other equation can also happen after [Cu(H2O)6] has reacted with 2NH3?
can react with an excess of ammonia