21.1 Buffer Solutions
No description yet. This curated deck is ready for daily study.
Card preview (8)
What is a buffer solution?
System which minimises pH changes on addition of small amounts of acid/base
What are the components of a buffer?
• Weak acid • It’s conjugate base
In which 2 ways can you prepare a weak acid buffer solution?
• Weak acid + salt • Partial neutralisation of weak acid
How can you prepare a weak acid buffer solution from a weak acid and it’s salt?
• Obtain weak acid • Obtain conjugate base from salt of weak acid. CH3COONa ⟶ CH3COO-(aq) + Na+(aq)
How can you prepare a weak acid buffer solution from partial neutralisation?
• Obtain weak acid • Partially neutralise using base to obtain salt, which can be used as base. AH + NaOH ⟶ ANa + H2O (partial)
How does adding small amounts of acid affect the equilibrium of a weak acid buffer solution?
[H+] increases more H+ react with conjugate base, A- equilibrium shifts to left (∵ backward reaction favoured)
How does adding small amounts of alkali affect the equilibrium of a weak acid buffer solution?
[OH-(aq)] increases OH- react with H+ equilibrium shifts to right (∵ forward reaction favoured) to restore [H+(aq)]
How can you find the pH of a solution using the acid dissociation constant?