pKa Table
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What is the pKa of alkanes? What factors contribute to this?
55; no contributing factors
What is the pKa of alkenes? What factors contribute to this?
45; hybridization
What is the pKa of allyl/benzyl? What factors contribute to this?
40; resonance
What is the pKa of amines? What factors contribute to this?
35; electronegativity
What is the pKa of diallyl/dibenzyl? What factors contribute to this?
35; resonance
What is the pKa of alkynes? What factors contribute to this?
25; hybridization
What is the pKa of carbonyls? What factors contribute to this?
20; resonance and electronegativity
What is the pKa of alcohols? What factors contribute to this?
15; electronegativity
What is the pKa of thiols? What factors contribute to this?
10; electronegativity and size
What is the pKa of 1,3,-dicarbonyls? What factors contribute to this?
20; electronegativity and resonance
What is the pKa of ammoniums? What factors contribute to this?
10; neutrality
What is the pKa of nitro? What factors contribute to this?
10; electronegativity, resonance, and induction
What is the pKa of peroxide? What factors contribute to this?
10; electronegativity and induction
What is the pKa of carboxylic acids? What factors contribute to this?
10; electronegativity and resonance
What is the pKa of strong acids? What factors contribute to this?
0>; electronegativity and resonance
What is the pKa of inorganic acids (H-X)? What factors contribute to this?
-5; size and resonance
What is the pKa of oxoniums? What factors contribute to this?
0; electronegativity and neutrality