Chapter 14-15
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Intermolecular forces
Forces that attract molecules to each other + attracting - Responsible for state of matter at room temperature
Electrostatic attraction
Intermolecular forces
Dipole
Molecule with a polar covalent bond (One part is charged +, one part is charged -) Temporary because electrons always moving
Hydrogen bonding (IMF)
Strongest Attraction between molecules containing very strong dipoles In molecules containing hydrogen bonded to a very electronegative element (H2O, NH3, HF)
Dipole-dipole bonding (IMF)
Middle strength Attraction between two dipole molecules In all dipoles when they get close to each other (H2S, HCl, HBr)
(London) Dispersion Forces (IMF)
Weakest Attraction between two non polar molecules In all molecules, but major force of attraction in two non polar molecules (CO2, Br2, I2)
Substance with ______ IMF will probably be a gas at room temperature
Weak
Substance with ________ IMF will probably be solid or liquid at room temperature
Strong
Vapor Pressure
Measured when a liquid is placed in a sealed container at measured temperature and allowed to evaporate. Air above liquid becomes saturated with vapor.
Equilibrium
For every molecule that evaporates, one condenses
When do liquids boil
When the vapor pressure = atmosphere pressure
As temperature of a liquid increases, vapor pressure above the liquid ______
Increases
When there is a lower atmospheric pressure, the vapor pressure needed to boil is _______ so it boils at a _______ temperature
Lower
Viscosity
A fluids resistance to flow
Surface tension
The intermolecular attraction between the molecules at the surface of a liquid
Sublimation
Solid > gas
Deposition
Gas > solid
Vaporization
Evaporation Boiling (Liquid > gas)
Triple point
Point at which all three states of matter coexist
Critical point
Point beyond which only gas is possible (supercritical fluid)
Normal freezing point
At 1 ATM pressure, point at which melt/freeze
Normal boiling point
At 1 ATM pressure, point at which boil/condense
Solution
Evenly mixed throughout Contains solute and solvent
Solvent
Substance in greatest amount in a solution