Definitions
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What are isotopes?
• Atoms of the same element which therefore have the same number of protons and electrons but a different number of neutrons
What is relative isotopic mass?
• The mass of an isotope relative to 1/12th of the mass of an atom of carbon-12
What is relative atomic mass?
• The weighted mean mass of an atom of an element relative to 1/12th of the mass of an atom of carbon-12
What is ionic bonding?
• The electrostatic attraction between positive and negative ions
What is an ionic lattice?
• A repeating pattern of oppositely charged ions
What is a covalent bond?
• The strong electrostatic attraction between a shared pair of electrons and the nuclei of the bonded atoms
What is electronegativity?
• The ability of a bonded atom to attract the bonding electrons in a covalent bond
What is a hydrogen bond?
• A special type of permanent dipole-dipole interaction found between molecules containing: • an electronegative atom (such as F, O and N) with a lone pair of electrons • a hydrogen atom bonded to an electronegative atom
What is periodicity?
• Repeating trends in the physical and chemical properties of elements across a period
What is first ionisation energy?
• The energy required for the removal of 1 mol of electrons from 1 mol of gaseous atoms of an element
What is metallic bonding?
• The strong electrostatic attraction between cations and delocalised electrons
What are giant covalent lattices?
• Networks of atoms bonded by strong covalent bonds
What is disproportionation?
• A redox reaction in which the same element is both oxidised and reduced simultaneously
What is the standard enthalpy change of formation?
• The enthalpy change that takes place when one mole of a compound is formed from its elements under standard conditions
What is the standard enthalpy change of combustion?
• The enthalpy change that takes place when one mole of a substance is reacted completely with oxygen under standard conditions
What is the standard enthalpy change of neutralisation?
• The enthalpy change that accompanies the reaction of an acid by a base to form one mole of H2O (l) under standard conditions
What is average bond enthalpy?
• When 1 mole of bonds of gaseous covalent bonds is broken
What is a buffer solution?
• A system that minimises pH changes on addition of small amounts of an acid or a base
What is lattice enthalpy?
• The enthalpy change when 1 mole of ionic lattice is formed from its gaseous ions
What is the definition of the standard enthalpy change of solution?
• The enthalpy change that takes place when 1 mole of a solute dissolves in water
What is the definition of the standard enthalpy change of hydration?
• The enthalpy change that takes place when 1 mole of gaseous ions form hydrated ions
What is entropy?
• A measure of the dispersal of energy in a system, that is greater the more disordered a system is
What is standard electrode potential?
• The e.m.f of a half-cell compared to a hydrogen half-cell
What are the transition elements?
• Elements that form at least one ion with a partially filled d-orbital (not scandium and zinc)