12 - acid-base equilibria
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brønsted-lowry acids
proton donors
brønsted-lowry bases
proton acceptors
dissociate.. strong acids and bases do what?
dissociate almost completely
conjugates any species that has gained a proton is..
the conjugate acid
conjugates any species that has lost a proton is..
the conjugate base
acid + base
salt + water
acid + metal
salt + hydrogen
acid + carbonate
salt + water + carbon dioxide
standard enthalpy change of neutralisation
enthalpy change when acid and base solutions react together to produce 1 mole of water ALWAYS EXOTHERMIC
[H⁺] pH
-log[H⁺]
ph [H⁺]
10⁻(pH)
(2) monoprotic acids
• dissociate to produce one H⁺ ion • conc of acid = conc of H⁺ ions
(2) diprotic acids
• dissociate to produce two H⁺ ions • conc of acid = 2 x conc of H⁺ ions
formula Kw
[H⁺][OH⁻]
what is Ka used for?
to find the pH of weak acids
(2) what are the assumptions for Ka?
• only a small amount of HA dissociates * [HA] eq ≈ [HA] start • all H⁺ ions come from the acid
(2) formula Ka
Ka = [H⁺][A⁻] / [HA] Ka = [H⁺]² / [HA]
does water dissociate weakly or strongly?
weakly H₂O ⇌ H⁺ + OH⁻
value of Kw
1.00 x 10⁻⁴
in terms of H⁺ concs what does pure water have?
equal concentrations of H⁺ and OH⁻ so Kw = [H⁺]²
Kw pKw
-log [Kw]
pKw Kw
10⁻ (pKw)
Ka pKa
-log [Ka]
pKa Ka
10⁻ (pKa)