Bonding
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Ionic bonding
• electrostatic attraction • between oppositely charged ions
Covalent bond
• electrostatic attraction • between shared pair of electrons • and nuclei of bonded atoms
Ionic lattice mpt
• electrostatic forces acting in all directions • lots of energy required to overcome bonds • high mpt and bpt
Ionic lattice conduction
• solid- ions held in fixed position • no mobile charge carriers • liquid- ions are mobile • able to conduct
Ionic lattice solubility
• greater the ionic charge the less soluble an ionic compound • water can overcome ionic bonds • attracted to polar ions
Dative covalent bond
• one atoms donates lone pair of electrons • electrostatic attraction between shared pair of electrons • and nuclei of bonded atoms
Draw N2
• triple bond between • lone pair on each
Draw H2CO
• double bond between CO • single between CH
Draw NH3BF3
• dative bond between N and B
Draw NH4+
• dative covalent bond • 1+ charge
Simple molecular mpt and bpt
• only have induced dipole-dipole forces • weak • require little energy to overcome • low mpt and bpt
Simple molecular conduction
• no mobile charge carrier, ions or electrons • can’t carry charge
Simple molecular solubility
soluble in non-polar solvents
Giant covalent structure examples
• Si8 • graphite • diamond • graphene • silicon dioxide SiO2
Giant covalent mpt and bpt
• high • large number of covalent bonds • large amount of energy to overcome
Giant covalent conductivity
• graphite and graphene can • delocalised electrons • free to carry charge
Electron pair repulsion theory
• electron pair repel each other round the central atom • depends on number and type of pairs • lone pairs repel more than bonded
Two bonded pairs
linear 180°
Three bonded pairs
Trigonal planar 120°
Four bonded pairs
Tetrahedral 109.5°
Five bonded pairs
Trigonal bipyramidal 120° and 90°
Six bonded pairs
90°
2 bonded pairs and 1 lone pairs
trigonal pyramidal 107°
2 bonded pairs and 2 lone pairs
angular(bent) 104.5°