som week 7
暂无描述。系统推荐的高质量记忆内容,适合每天坚持背诵学习。
卡片预览 (10 张)
give equation for dipole moment and the units of each value
μ = Qr μ - coulomb metres, Cm or debyes, D, conversion is given in data table Q - coulombs, C r - distance in metres between the two charges, m
give the equation for the addition of two dipole moments
μ = √(μ₁² + μ₂² + 2μ₁μ₂cosθ) basically cos rule
give the equation for the 𝑥, 𝑦 and 𝑧 components of a dipole how is the overall dipole calculated from these components?
μ𝑥 = ΣQj 𝑥j μ𝑦 = ΣQj 𝑦j μ𝑧 = ΣQj 𝑧j j meaning of each atom Qj = charge of each atom in the molecule 𝑥j = 𝑥 of each atom in the molecule so it is the sum of the each atom’s charge x position overall μ = √(μ𝑥² + μ𝑦² + μ𝑧²)
what symbol is used for an induced dipole? what is an induced dipole proportional to and what two equations are derived from this?
μ* μ* ∝ size of electric field, E μ* = ɑE μ* = 4πℇ₀ɑ’E 4πℇ₀ = scaling constant, ℇ₀ is vacuum permittivity which is given ɑ and ɑ’ = polarisability and in the last equation the units are m³ E = electric field, V/m
give the equation for the interaction between two charges in a vacuum how do we get the value for V in one mole of interactions?
V = Q₁Q₂/4πℇ₀r V = potential energy, J Q = charge r = distance between the charges, m V x NA = J/mol
what must V be divided by when an interaction takes place not in a vacuum?
relative permittivity ℇr = ℇ/ℇ₀ V/ℇr
give the equation for a dipole-dipole interaction that is: • linear • at an angle
V = -μ₁μ₂/2πℇ₀r³ V = -μ₁μ₂/4πℇ₀r³ (1 - 3cos²θ)
give the equation for charge-dipole interaction that is: • linear • at an angle
V = -μ₁Q₂/4πℇ₀r² V = -μ₁Q₂/4πℇ₀r² x cosθ distance is taken from the charge to the middle of the dipole (midpoint between two charges that make the dipole)
what is the charge of an electron?
-1.602 x 10-19 C
how do convert from nm - m? pm - m?
1 nm = 10-9 m 1pm = 10-12 m