Ch.11 Basic Componants Of Organic Chemistry
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Homologous series
A series of compounds with the same functional group whose successive members differ by a -CH2 group
Functional group
Group of atoms responsible for the characteristic chemical properties and reactivity of a compound
Alkane general formula
CnH2n+2
Alkene general formula
CnH2n
Alkenes
C=C -ene
Haloalkanes
-Cl -Br -I
Alcohols
-OH -ol
Aldehydes
Carbonyl functional group -C=O I H -al
Ketones
Carbonyl functional group C I C=O -one I C
Carboxylic acid
Carboxyl functional group (COOH) C=O I -oic acid OH
Esters
R-C=O I O-R -oate
Acyl chlorides
-C=O I Cl
Amines
1• 2• 3• R-N- H R-N-H R-N-R I I I H R R -amine
Amides
N bonded to a carbonyl -C=O I N
Aliphatic
C atoms are joined In a chain
Alicyclic
C atoms are joined in a ring
Aromatic
Contains a benzene ring
Structural isomers
Compounds with the same molecular formula but different structural formulas
Functional group isomer
Same molecular formula but different functional groups
Homolytic fission
When a covalent bond breaks, each bonded atom takes 1 electron from the bond, creating 2 radicals
Heterolytic fission
Covalent bond breaks, 1 of the bonded atom takes both electrons from the bond, becoming a negative ion
A radical
An atom or group of atoms with an unpaired electron
Nucleophiles
Electron pair donors They like + charge Electron rich
Electrophiles
Electron pair acceptor They like - charge Electron poor