Chapter 10B - Infrared Radiation
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What is Infrared Radiation?
• involves interaction of IR w/ matter wavelength: 700nm-1mm • qualitative analysis technique for functional groups, carbon bonds & types of covalent bonds
How does Infrared Radiation work?
• IR energy not enough to promote electrons to higher energy levels • Enough to cause covalent bonds to bend & stretch • Stretch/bend/vibration of covalent bond produces vibrational energy levels
What does amount of IR energy absorbed or released depend on?
• types of bonds (polarity) • environment • other bonds in molecule
Infrared spectrum
x-axis = wavenumber y-axis = transmittance - trough/peak appears when energy absorbed by a covalent bond - deeper peak = stronger the absorbance
Transmittance
opposite of absorbance 100% transmittance = no light absorbed
Fingerprint region
500-1400cm-1 - qualitative - identify compound by comparing spectrum of unknown with known
How does Infrared Radiation work?
• wavelength within IR region of electromagnetic spectrum strongly absorbed by particular covalent bond • molecules move from ground state to excited vibrational energy states • gives an infrared spectrum