Structure 2.2 - Covalent
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What is a covalent bond?
electrostatic attraction of the positive nucleii for the region of negatively charged high electron density
How will atoms in a covalent bond achieve a lower energy state?
sharing electrons and acquiring a full valence shell
What happens to the bond length as the number of bonds increases?
bond length decreases since increasing numbers of electron pairs shared causes the positive nucleii to come closer
What is the octet rule?
the filling of the valence shell to achieve 8 electrons
What is the bond energy?
a measure of the strength of the electrostatic force of attraction between the atoms energy required to break the bond
Which are stronger, pi or sigma bonds, and why?
sigma are stronger, in a pi bond the electrostatic attraction is off the axis
What are the consequences of pi bonds being weaker?
they are more reactive eg: enable alkenes and alkynes to undergo a wide range of chemical reactions by addition
What are carboxylic acids?
homologous series of organic chemicals with the carboxyl group
What is the carboxyl group?
COOH
What are the consequences of hybridisation?
bonds become shorter, more stable, and more difficult to break
What are electron domains?
regions of high electron density surrounding an atom
4 electron domains, no lone pairs
Tetrahedral 109.5
4 electron domains, 1 lone pair
Trigonal pyramidal 107
4 electron domains, 2 lone pairs
Bent 104.5
4 electron domains is always in electron domain geometry
tetrahedral
3 electron domains, no lone pairs
Trigonal planar 120
2 electron domains
Linear 180
3 electron domains, one lone pair
Non-linear bent 117
What shapes exist in E.D geometry?
ONLY tetrahedral trigonal planar linear (diatomic)
How does the expansion of the octet occur?
elements in the 3rd and lower periods of the p block can promote one or more electrons from a doubly filled s/p orbital into an unfilled d orbital
5 electron domains, no lone pairs
trigonal bipyramidal 120 and 90
5 electron domains, 1 lone pair
seesaw <90 <120
5 electron domains, 2 lone pairs
T-shape <90
5 electron domains, 3 lone pairs
Linear 180