Transition metals - 5
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Define a transition element
A D-block element that can form at least one stable ion with an incomplete d sub-shell
which metals in the d-block aren’t transitions metals
Scandium and zinc
Why is zinc not a transition metal
Zinc only forms 2+ ions, losing electrons from the 4s2 So it keeps a full 3d sub-shell
Why is scandium not a transition metal
Scandium only forms 3+ ions Causing it to have an empty 3d sub-shell
Define a complex ion
A metal ion surrounded by co-ordinately bonded ligands
What is a ligand
An atom, ion or molecule that donates a pair of electrons
What is the coordination number
The number of coordinate bonds that are formed to a central metal atom/ion
What do 6 coordinate bonds mean
An octahedral shape 90 degree bond angle
what do 4 coordinate bonds mean
Tetrahedral - 109.5 OR Square Planar - 90
How are ligands named
Based off the number of lone pairs 1- monodentate 2 - Bidentate 2 + - multidentate
What isomerism can complex ions show
Optical isomerism Cis-Trans isomerism
what is cis-platin
A complex of platinum with two chlorides and two ammonia molecules Square planar shape
How can cis-platin be used as an anti-cancer drug
The chloride ligands are easily displaced And bond to two nitrogen atoms on the DNA molecule of the cancer cell This prevents DNA from reproducing
What is the disadvantages of cis-platin
Can prevent normal cells from reproducing Can cause kidney damage
What colour ions does Ti3+ and Ti 2+ form
Ti3+ - Purple Ti2+ violet
What colour ions does VO2+ form
VO2+ - yellow
What colour ions does Cr2O7 2- and Cr3+ form
Cr2O7 2- - Orange Cr3+ - Purple
What colour ions does MnO4-form
MnO4- = purple
what colour ions does Fe3+ and Fe2+ form
Fe3+ = yellow Fe2+ = pale green
What colour ions does Co2+ form
Co2+ = pink
What colour ions does Ni2+ form
Ni2+ = green
What colour does ions does Cu2+ form
Cu2+ = pale blue
What is the colour change for the ligand substitution of Cu2+
Pale blue solution to a pale blue precipitate
What is the colour change for the ligand substitution of Fe2+
A pale green solution to a dark green precipitate