Organic Analysis: Test Tube Reactions
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What reagent is used to test for an alkene?
Bromine water
Observation for a positive alkene test with bromine water?
Orange/brown solution decolourises to colourless
Why does bromine water decolourise with alkenes? (Br2 + acrs. C=C - add. rctn.)
Bromine adds across the C=C double bond in an addition reaction
How do you test for a halogenoalkane? (add. NaOH + wrm - add dlte. HNO3 acdfy. - add AgNO3 - pos. rslt. frm. prcpte. AgX slvr hlde. frms)
• Add NaOH (aq) and warm • Then add dilute HNO3 to acidify • Then add AgNO3 (aq) A positive result will form a precipitate of AgX (silver halide) forms
What reagent is used to oxidise alcohols in organic tests?
Acidified potassium dichromate (H⁺/K₂Cr₂O₇)
What is the colour change when acidified potassium dichromate oxidises a primary or secondary alcohol?
Orange to green
What does it indicate if acidified potassium dichromate remains orange after adding an alcohol?
The alcohol is tertiary (no oxidation occurs)
Why do tertiary alcohols not change the colour of acidified potassium dichromate?
They cannot be oxidised under normal conditions
What happens when propan - 1 - ol/propan - 2 - ol is hated with acidified potassium dichromate?
The solution turns from orange to green due to oxidation
What reagent is used to distinguish between an aldehyde and a ketone?
Tollens’ reagent
What is the positive result when Tollens’ reagent reacts with an aldehyde?
Formation of a silver mirror
Why do aldehydes react with Tollens’ reagent but ketones do not?
Aldehydes are readily oxidised, whereas ketones are no
What is the result when Tollens’ reagent is added to a ketone?
No visible change
How can you test for a carboxylic acid functional group?
Add a carbonate (e.g. sodium carbonate)
What is the observation when a carboxylic acid reacts with sodium carbonate?
Effervescence (bubbles of CO₂ gas)
What are the products when a carboxylic acid reacts with a carbonate?
A salt, carbon dioxide and water