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Part 3

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Total cards: 10•Content version: v4•Public deck•Updated: 8/1/2026

Card preview (10)

#1
Front (Question)

1) NaBH4 2) H3O+

Back (Answer)

A reducing agent. It is more selective and easier to handle, but will NOT reduce carboxylic acids and esters. Will reduce aldehydes and ketones.

#2
Front (Question)

1) Lithium Aluminum Hydride (LiAlH4 or LAH) 2) H3O+

Back (Answer)

A reducing agent. Strong and powerful. More difficult to work with. Will reduce all aldehydes, ketones, carboxylic acids, and esters.

#3
Front (Question)

1) BH3 2) H2O2, OH-

Back (Answer)

Hydroboration BH3 adds readily to double bonds. Second step is oxidation-hydrolysis in an ANTI-markovnikov, syn orientation. In presence of peroxides will convert to alcohol.

#4
Front (Question)

Cold, dilute KMnO4

Back (Answer)

An oxidizing agent. Produces 1,2 diols (vicinal diols). a.k.a. glycols with syn orientation.

#5
Front (Question)

Alkene + Br2/CCL4 –> ?

Back (Answer)

Addition of halogens to double bonds is rapid. Double bond is nucleophile and attacks X2. Addition is anti, because X- attacks cyclic halonium ion in SN2 displacement.

#6
Front (Question)

AlCl3 + X2 or acyl group –?

Back (Answer)

AlCl3 is a lewis acid. X2 in presence of lewis acid (FeCl3, FeBr3, AlCl3) produces monosubstituted products in good yield. AlCl3 + acyl groups = Friedel-Crafts Acylation. will incorporate acyl group.

#7
Front (Question)

Zwitterion

Back (Answer)

An ion with both a positive and negative charge.

#8
Front (Question)

Alcohol + Carboxylic acid –> ?

Back (Answer)

Makes an ester

#9
Front (Question)

Henderson-Hasselbalch Equation

Back (Answer)

pH = pKa - log ([conjugate base]/[conjugate acid])

#10
Front (Question)

Nonpolar Amino Acids

Back (Answer)

Valine, Alanine, Isoleucine, Leucine, Proline, Phenylalanine, Glycine, and Tryptophan. non - TV PIG PAL”