Fibres
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What are fibres?
• basic unit of yarns and threads which then turn into fabrics, garments, textiles
Where are fibres found?
• clothing • bedding • carpets • curtains • bandages • fibreglass • loft insulation • seatbelts
What are natural fibres?
• can be plant, animal or mineral based • also known as staple fibres
What are some examples of natural plant fibres?
• cotton • linen • hemp • coir • flax
What aresome examples of natural animal fibres?
• silk • wool • cashmere • camel • angora
What is an example of mineral fibre?
asbestos
What is cotton made from?
cellulose (polymer)
What is silk made from?
sericin/fibroin (polymeric protein)
Why is silk shimmery?
due to prism-like structure
Asbestos
• naturally occuring silicate material • carcinogenic • sound absorbing, strong, cheap, fire resistant, electrical insulating
What are synthetic fibres?
• also called filament fibres • longer than natural fibres • polymer with very high length to diamter ratio
What are some examples synthetic fibres?
• polyester • nylon • acrylic • polypropylene • glass fibre (made from silica which is natural but process of making it isnt)
How are synthetic fibres made?
• extruded through a spinneret device - polymer is pushed through tiny holes that are differently shaped • fibres spun into bundles called filaments • can alter the characteristics with different spinning techniques
What are the recovery considerations for fibres?
• may become dislodged quickly after deposition • air dry wet clothing in controlled environment • store in paper bags to prevent mould growth • double package • submit whole item • druggists fold for small fibres • never package with debris from the scene
What is the analytical workflow for fibres?
• gross examination, recovery and collection • preliminary evaluation of physical characteristics • physical fit assessment - most probative value • microscopic techniques • microspectrophotometry (UV-Vis) - colour determination • infrared spectroscopy - manufactured fibres • Raman spectroscopy - dyes and pigments
What are some non-routine techniques that arent recommended and are only used after everything else has been exhausted?
• thin layer chromatography • pyrolysis GS-MS • HPLC • melting point • microchemical tests ALL DESTRUCTIVE METHODS
What are some things to look for when analysising fibres?
• surface treatments • dye penetration • diameter and length • cross-section • chemical composition (type, polymer) • texture • colourant/dye - colour, type, how applied, weathering • natural or synthetic and type • striations (lines down the fibre) and pitting (holes/damage) • direction of yarn twist • threat count • coatings • scale protrusion on animal fibres
What does IR/Raman look at on fibres?
• colour - different dyes/pigments • chemical composition
What does dye uptake depend on with fibres?
• when the fibre is dyed during the manufacturing process - before, after being spun or after garment construction
What does the transfer of fibres depend on?
• nature of contact • multiple association mitigate coincidental transfer • new fabrics possess loosley adhering fibres • old/damaged fabrics may shed more • tightly fibres shed less than staple fibres • background and persistence considerations
What are the issues with fibres as trace evidence?
• cant state that it is unique • few databases for origin • often overlooked as difficult to locate • expensive, time-consuming skilled analysis
What some microscopic techniques for fibres?
• stereoscopic • comparison • polarised • fluorescence • brightfield • thermal (destructive) • SEM and TEM • crystallography and diffraction
What are some physical fit and gross characteristics in fibres?
• surface treatments • dye penetration • diameter • chemical composition • cross section • texture • colourant/dye - colour, type, how applied, weathering
What is a microscopic technique of cotton?
twisting shape