C-6 The rate and extent of chemical change
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• What is the the rate of reaction
• How fast the reactants are changed in products
• what are the equations used to calculate rate of reaction
mean rate of reaction = quantity of reaction used//time taken Sanity ion product formed// time taken
What must happen in order for a reaction to take place
• Must collide with enough energy -
What is collision theory
• The more collisions there are the faster the rate of reaction • the energy transferred during a collision. Particles have to collide with enough energy for the collision to be successful • Activation energy- the amount of energy needed to break to bonds
What increases the rate of reaction on a theory basis
• More collisions increase the rate of reactions
How does temperature effect the rate of reaction
• When temperature increase the kinetic energy store increases and they move faster • As they are moving faster they will collide more frequently • The faster they move the more energy they gave so more collisions will have enough energy to make the reaction happen
What effect does concentration and pressure have on a reaction
• IF a solution is more concentrated it means there are more particles knocking about in the same volume of water • Similarly when pressure increases it means same number of particles occupy smaller space • makes collisions more frequent- therefore rate of reaction increases.
What effect does surface area have on rate of reaction
• IF reactants is solid then breaking it up will increase surface area to volume ratio • This means that for the same volume of solid particles will have more area to work on- so reactions will be more frequent
• What is a catalyst
• Substance that speeds up a reaction without being used up itself within the reaction - not part of overall equation • • Different catalysts are needed for different reactions- but they all decrease activation energy- provide an alternate pathway- lower energy needed
• How do catalysts effect the rate of reaction
• Different catalysts are needed for different reactions- but they all decrease activation energy- provide an alternate pathway- lower energy needed
• What are enzymes
• Biological catalysts - speed up rate of reaction in living things
• What are the steps in measuring change in rate of reaction
• Colour change and precipitation • Change in mass- gas • Volume of gas given off
How do you investigate rat elf rate of reaction in precipitation and colour
• Visual change • Observe a mark through solution and see how ;omg to tales to disappear- faster it takes faster rate • If reactants are coloured and products colourless you can see how long it takes to gain or loose colour • Subjective results • Cant plot
How do you investigate rate of reaction using change in mass
• measuring speed that produces a gas • As gas is related the mass leaving is measured in change in mass balance • IF take measurements at regular intervals a graph can be plotted • Most accurate- gas goes into room
• How do you investigate rate of reaction using gas syringe
• Gas given off • More gas given off means faster rate • nearest cm 3 • Graph • Can low plunger out
What is the two rates experiments method
• Add set volume of HCL to conical flask • Add magnesium while on a mass balance • Record mass change at set intervals • Test with other concentrations • Plot on same graph and compare
• What is is the black cross test
• Both clear- go yellow • Add set amount of sodium • Place piece of paper in • Test time to no longer see black cross for different concentrations • No graph
• How can you calculate mean rate of reaction
• Overall change//overall time
• How do you find rate of reaction at a particular point
• Draw a tangent and find relative gradient
• What are reversible reaction
• In some chemical reactions the products can react to produce original reactants
• How can reversal reactions be represented
• A + B <=> C + D
• How can the direction of reversible reactions be change
• By changing the conditions e. g Ammonium chloride <====> Ammonium+ hydrogen to move left to right - heat to remove left to right- cool
• What are the energy changes in a reversible reaction
• A reversible reaction is endothermic in one direction and exothermic in another. Same amount of energy transferred
• What is an example of exothermic and endothermic reversible reactions
• Hydrated copper sulfate <=====> Anhydrous copper sulfate+ water Left to right- endothermic Right to left- exothermic