TM: Structure
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What is a transition metal?
Element that had an incomplete d sub-shell in either its atoms or one of its common ions
Properties of transition metals
Variable oxidation states Catalytic action Coloured compounds Formation of complexes
Ligand definition
Particle with lone pair of electrons that bond to metals by a co-ordinate bond
Complex definition
Metal ion with co-ordinately bonded ligands
Co-ordination number definition
Number of co-ordinate bonds from ligands to metal ions
Properties of a linear complex
2 co-ordination number Ag+
Properties of a square plane complex
4 co-ordination number Pt2+ & Ni2+
Properties of a tetrahedral complex
4 co-ordination number Larger ligands unable for 6 to fit eg. Cl-
Properties of an octahedral complex
6 co-ordination number
Properties of hexa-aqua ion complexes
6 water ligands bonded to a transition metal ion Contains water molecules
Complex ion, ligand and counter ion of NA3[AuF6]
Complex: [AuF6]3+ Ligand: 6F- Counter: 3Na+
What is a unidente ligand?
Ligands which form one co-ordinate bond to a metal ion
What is a bidentate ligand?
Ligands which form two co-ordinate bond to a metal ion
What isomerism occurs in octahedral or square planar? Requirements?
Cis-trans isomerism 2 ligands of one type that are different to others
Cis-trans isomerism of Pt(NH3)2Cl2 and their names
Cisplatin - Cl and NH3 molecules next to each other Transplatin - Cl and NH3 molecules opposite eachother
What isomerism occurs only in octahedral? Requirements?
Optical isomers 3 bidentate ligands
Example of small ligands
NH3 & H2O
Example of larger ligand
Cl-
What does Tollen’s reagent contain and how does the oxidation state change?
[Ag(NH3)2]+ Ag+ reduced to Ag in silver mirror