1.9 Chemical Analysis
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Pure substance
A single element or compound not mixed with any other substance
Transition between solid - gas through its melting and boiling
Solid substance is heated, temperature increases until its melting point - the temperature remains constant while the substance melts even though it is still being heated The solid changes to a liquid, it’s temperature increasing until its boiling point - the temperature remains constant while the substance boils even though it is still being heated The liquid becomes a gas and its temperature increases
Melting and boiling of pure substances
At fixed/specific temperatures - this can be used to distinguish substances from mixtures
Melting and boiling of impure substances
Over a range of temperatures - has a lower melting point as the bonds between particle are weaker due to impurities disrupting regular lattice arrangement. more impure the lower the melting point - an impure liquid with a substance dissolved in it has a higher boiling point as the liquid molecules re more attracted to the dissolved substance - have a stronger bond. more impure the higher the boiling point
Formulations
A mixture which has been designed as a useful product
How are formulations made
Mixing together several different substances in carefully measured quantities to ensure the product has the required properties
Alloys as formulations
Mixture of at least 2 elements, one being a metal eg 18 Carat gold
Tablets as formulations
Drug with corn starch (binding) and lubricant (swallow) eg calpol
Fertilisers as formulations
Mixture of nitrogen, phosphorus, potassium compounds eg NPK fertilisers
Soluble
Dissolves in water
Insoluble
Does not dissolve in water
Solute
Soluble substance which dissolves
Solvent
Liquid in which solute dissolves
Solution
Mixture of solute dissolved in a solvent
Miscible
Liquids which mix eg alcohol and water
Immiscible
Liquids which don’t mix eg water and oil
Filtrate
Filtered solution
Residue
Solid which remains on the filter paper
Distillate
Liquid that is collected in distillation
Evaporation def
When a liquid is heated and changes state onto a gas
Condensation
When a gas cools and changes state into a liquid
Filtration as a separation technique
Separates an INSOLUBLE substance from a LIQUID eg sand and water - The filter paper holds back the solid particles (residue) while allowing the liquid (filtrate) to drip through
Evaporation as a separation technique
Separates a SOLUTE from a SOLVENT eg salt and water - the solution is gently heated until some solvent evaporates - this leaves behind a saturated solution, and when left to cool forms crystals (crystallisation)
Simple distillation as a separation technique
Separates a SOLVENT from a SOLUTION eg water from salt water or ONE of TWO MISCIBLE LIQUIDS eg water and ethanol SEE NOTE!! - the solution is heated, solvent vapour cools and becomes a liquid in the condenser and drips into a beaker. the solute stays behind • the substance with the lowest boiling point will be distilled first if using miscible liquids with largely different boiling points • water must continue to move in and out of the condenser to ensure it is filled at all times • anti-bumping granules are added to the contents of the flask to promote smooth boiling NOTE if done using ethanol and water, the ethanol will evaporate first at 79 degrees but water will begin to evaporate too, meaning the ethanol distillate will be impure. To prevent the fractional distillation is used instead