Module 5: 20 & 21
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What is a Bronsted-Lowry acid?
A proton donor
What is a Bronsted-Lowry base?
A proton acceptor
What is a conjugate acid-base pair?
Contains 2 species that be interconverted by transfer of a proton HCl + H2O ⇌ H3O+ + Cl- NH3 + H2O ⇌ NH4+ + OH-
What are some common acids and their conjugate bases?
HCl -> Cl- HNO3 -> NO3- H2O -> OH- NH4+ -> NH3 H3O+ -> H2O
Why is water special?
Can act as an acid or a base (accept and donate protons) - Amphoteric
What is the type of acid linked to?
The number of hydrogen ions that can be replaced per molecule in an acid-base reaction Monobasic acid: HCl & CH3COOH Dibasic Acid: H2SO4 Tribasic acid: H3PO4
What is the general redox reaction involving acids?
Acid + metal -> salt + hydrogen gas (MASH)
What are the 3 neutralisation reactions involving acids?
Acid + alkali -> salt + H2O Acid + carbonate -> salt + H2O + CO2 Acid + metal oxide -> salt + H2O
How can molecules accept protons?
Lone pairs of electrons -> dative covalent bonds
What is a strong acid?
HA -> H+ + A- • strong tendency to donate H+ ions • fully dissociate in aqueous solution • equilibrium lies to the right
What does the pH scale show?
the relationship between pH and hydrogen ion concentration [H+(aq)]
How is pH calculated?
pH = -log[H+(aq)] • give all answers to 2 decimals places
How can the pH of a strong acid be calculated?
• directly from the conc of the acid because the acid completely dissociates into ions • H+ ion conc is equal to the conc of the strong acid in question HA(aq) -> H+(aq) + A-(aq) [HA(aq)] = [H+(aq)]
How is the pH changes on dilution calculated (1)?
diluted concentration = original moles / volume after dilution
How is the pH changes on dilution calculated (2)?
diluted concentration = original conc x (volume before dilution / volume after dilution)
What is a weak acid?
HA ⇌ H+ + A- • weaker tendency to donate H+ • partially dissociate in aqueous solution • equilibrium lies on the left • strength of a weak acid is given by the acid dissociation constant (Ka)
How is Ka calculated?
Ka = [H+][A-] / [HA] units: moldm-3
What is Ka?
The acid dissociation constant
What do the Ka values represent?
• The larger the value of Ka, the stronger the acid - The smaller the value of Ka, the weaker the acid
When does Ka change?
Changes with temperature (standard temp is used, 298K)
How is pKa calculated?
pKa = -log(Ka)
How is Ka calculated with pKa values?
Ka = 10^-pKa
How is [H+(aq)] calculated from Ka?
10^-Ka
What do the pKa values indicate about the acid?
• the larger the pKa value, the weaker the acid - the smaller the pKa value, the stronger the acid