metals and alloys
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what are metals and alloys used for
• partial denture framework = CoCr, type IV gold • crowns = stainless steel • denture base =stainless steel • orthodontic appliance = NiTi • restorations = amalgam
why is amalgam different to all the other metals and alloys
• as it undergoes a setting reaction and the rest don’t
what does stainless steel being a denture base show of alloys
• shows alloys are versatile - able to take on complex shapes
what are the properties of interest of metals and alloys
• strength • rigidity • elastic limit • ductility • hardness
what is the downside of alloys
• their aesthetics
what is the definition of a metal
• aggregate of atoms in crystalline structure - building blocks of alloys
what is the definition of alloys
• combination of metal atoms in a crystalline structure
what is the stress/strain curve
• shows that when you increases stress you increase strain = change shape • shows the fracture stress, elastic limit and UTS of the material • also shows the malleability and ductility of material
what is the UTS
• ultimate tensile strength
what is ductility
• amount of plastic deformation prior to fracture - measure of extent material can be shaped
what is malleability caused by
• if apply compressive stress
what does the crystalline structure depend on
• history = method of production, structure depends on how you produce it • shaping = crucial for dental application (cold working, swaging)
what factors can affect mechanical properties
• crystalline structure = lattice of atoms - grain size and grain imperfections = grain is a single crystal
what is a grain
• a single crystal with atoms orientated in given directions (dendrites)
what are the 3 crystal structures
• cubic = simple cubic and relate structures • face-centered cubic = cubic close packed and related structure • body-centred cubic = body centred cubic and relate structures • metals have atoms positioned at regularly arranged sites
how do metals cool
• alloys start molten in a container and are then allowed to cool down • reaches a plateau where it goes from liquid to solid state and maintains temperature until all molten metal is now solid then it cools down again
how do crystals grow
• atoms at these sites act as nuclei of crystallisation • crystals then grow to form dendrites = atoms cool around the nuclei • crystals (or grains) grow until they impinge on other crystals and then stop growing • dendrites grow until they impact on another
what is the area called where dendrites meet
• grain boundary
what do the size and shape of grain boundaries depend on
• how it is processed - can be in all different sizes = sizes can also affect properties
what are the grains called if crystal growth is equal in all dimensions
• equi-axed grains
what are some grain structures other then equi-axed
• radial = molten metal cooled quickly in cylindrical mould - fibrous = wire pulled through die = cold worked metal/alloy
what is quenching
• fast cooling • more nuclei of crystallisation and lots of grains are produced • mechanical properties are enhanced = best you can get
what is produced from slow cooling
• few nuclei - large coarse grains = weaker
what do nucleating agents do
• help crystallisation process • impurities or additives act as foci for crystal growth • using these is another way in controlling grain size