4.2.1 alcohols
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distillation of primary alcohol
Primary alcohol > aldehyde potassium dichromate (VI) solution and dilute H2SO4 Warm gently and distil out the aldehyde as it forms Orange dichromate ion (Cr2O7 2-) reduces to green Cr3+ ion
Reflux primary alcohol
Primary alcohol > carboxylic acid Reagent: potassium dichromate (VI) solution and dilute H2SO4 Conditions: use excess dichromate, heat under reflux Orange dichromate ion > green Cr3+ ion + H2O, 2 [O]
Reflux of secondary alcohol
Secondary alcohol > ketone Potassium dichromate (VI) and dilute H2SO4 Heat under reflux Orange dichromate to green Cr3+ Ion
Alcohol and dehydrating agents
Alcohol > alkene Concentration sulfuric or phosphoric acid - acts as dehydrating agent Conditions : warm (under reflux) Type of reaction: acid catalysed elimination
Alcohol to haloalkane
Concentrated sulfuric acid and sodium halide