PHYSICAL CHEM - ACIDS AND BASES
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What is a Bronsted-Lowry acid?
a proton donor
What is a Bronsted-Lowry base?
a proton acceptor
What is a strong acid?
an acid that completely dissociates into H^+ ions/ionises in water/aqueous solution
What is a weak acid?
an acid that only partially dissociates into H^+ ions/ionises in water/aqueous solution
What is a strong base?
a base that completely dissociates into OH^- ions/ionises in water/aqueous solution
What is a weak base?
a base that only partially dissociates into OH^- ions/ionises in water/aqueous solution
Where does equilibrium lie when strong acids/bases dissociate into their ions?
extremely far to the right
Where does equilibrium lie when weak acids/bases dissociate into their ions?
to the left
What is the equation for the dissociation of water?
H2O + H2O ⇌ H3O^+ + OH^-
Where does equilibrium lie in the dissociation of water and why?
• far to the left • only dissociates a tiny amount
What is the equation for pH?
pH = - log [H^+]
What is the equation for the conc. of H^+ ions?
[H^+] = 10^-pH
What is the equation for Kw?
Kw = [H^+][OH^-]
What is the value of Kw at 298K/25°C?
1 x 10^-14
How does the pH of water change as temp increases and why?
• as temp increases water becomes more acidic • the forward reaction in the equilibrium of water is endothermic and is therefore favoured when temperature of the water increases • therefore more H^+ ions are produced
What is Ka?
• weak acids and bases only slightly dissociate in solution to form an equilibrium mixture • therefore the reaction has an equilibrium dissociation constant (Ka)
What is the equation for Ka?
Ka = [H+][A-]/[HA]
What is the equation for pKa?
pKa = - log (Ka)
How can you find the pH of a weak acid/base when HA is in excess?
use [HA] and [A^-] along with Ka to find [H^+], then find pH
How can you find the pH of a weak acid/base when A^- is in excess?
use Kw to find [H^+], then find pH
How can you find the pH of a weak acid/base when HA = A^-?
pKa = pH so find pKa
What is a titration curve?
• a graph that shows how pH of a solution changes during an acid-base reaction
What are the 4 types of titration curve?
• strong acid + strong base • strong acid + weak base • weak acid + strong base • weak acid + weak base
What is a buffer solution?
• a solution that minimises changes in pH when small amounts of an acid/base are added • work by neutralising added H^+/OH^- ions