Halogens
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What are the features of flourine
• Very pale yellow gas • Highly reactive
What are the features of chlorine
• Greenish, reactive gas • Poisonous in high conce
What are the features of bromine
• Red liquid • Gives off dense brown/orange poisonous fumes
What are the features of iodine
• shiny grey solid sublimes to purple gas
What is the trend in boiling and melting point as you go down group 7
• Increases down the group • Molecules get larger • More electrons and so have more van der waals forces between the molecules • More energy is required to break the van der waals forces.
What is the trend in electronegativeas you go down group 7
• Electronegativity decreases • Atomic radius increases due to the increasing number of shells • Nucleus is therefore less able to attract the bonding pair of electrons
Explain how displacement reactions of halide ions by halogens
• A halogen that is a strong oxidising agent will displace a halogen that has a lower oxidising power from one of its compounds.
What is the trend of oxidising strength as you go down group 7?
• Oxidising strength decreases down the group
What is an oxidising agent?
• Electron pair acceptors
What ions does chlorine displace
• bromide ions • Iodide ions
What ions does bromine displace
• ONLY iodide ions • NOT chloride ions
What ions does iodine displace
• NO ions
Explain the reaction when chlorine reacts with potassium chloride Give the observation
• NO reaction • As chlorine cant displace its own iodide • Observation - Pale green solution
Explain the reaction when chlorine reacts with potassium bromide Give the observation
• Chlorine displaces bromide ions • Observation - Yellow solution
Explain the reaction when chlorine reacts with potassium iodide Give the observation
• Chlorine displaces iodine ions • Observation - Brown solution
Explain the reaction when bromine reacts with potassium chloride Give the observation
• Yellow solution, no reaction
Explain the reaction when bromine reacts with potassium chloride Give the observation
• NO reaction • Bromine cannot displace chloride ions • Observation - yellow solution
Explain the reaction when bromine reacts with potassium bromide Give the observation
• NO reaction • Bromine cannot displace bromide ions • Observation - Yellow soluton
Explain the reaction when bromine reacts with potassium iodide Give the observation
• Bromine displaces iodide ions • Observation - Brown solution
Explain the reaction when iodine reacts with potassium chloride, potassium bromide and potassium iodide Give the observation
• NO reaction for all reactions • Observation - Brown solution
What gives the colour of the solution in a displacement reaction
• The free halogen present in the solution
What colour is the solution where chlorine is the free halogen?
• pale green solution
What colour is the solution where bromine is the free halogen?
• Yellow solution
Show the ionic equation of chlorine reacting with bromide ions