atomic structure
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isotope
atoms of the same element with the same atomic number but different mass numbers (different number of neutrons)
orbital
volume of space around a nucleus in which there is a high possibility of finding an electron
ionisation energy
energy required to remove one mole of electrons from one mole of an element in its gaseous state
first ionisation energy
the enthalpy change when one mole of gaseous atoms forms one mole of gaseous ions with a single positive charge
second ionisation energy
enthalpy change when one mole of gaseous ions with a single positive charge forms one mole of gaseous ions with a double positive charge
atomic number, Z
is the number of protons in the nucleus.
mass number, A
is the total number of protons and neutrons in the atom
4 steps in TOF
• Ionisation • acceleration • flight tube • detection
Two form of ionisation in a TOF
electron impact electrospray ionisation
KE equation
1/2 x m x v^2
3 main factors affecting ionisation energy
1.The attraction of the nucleus • The distance of the electrons from the nucleus • Shielding of the attraction of the nucleus
electron impact
An electron gun fires high energy electrons at the sample This knocks out an outer electron
Electro spray Ionisation
sample is dissolved in a volatile, polar solvent, injected through a fine needle giving an aerosol and the molecule gains a proton
what does m/z stand for
mass/charge ratio
Nucleons
Protons and neutrons – the sub-atomic particles found in the nuclei of atoms.
atom
the smallest part of an element that can exist
nuclear charge
total charge of all protons in the nucleus