C3.7 - Giant covalent structures
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giant covalent structures
huge 3D network of covalently bonded atoms
Properties of giant covalent structures
• insoluble • very high melting/boiling points • hard (except graphite) • cannot conduct electricity (except graphite)
Bonding in graphite
-1 carbon atom is covalently bonded to 3 other C atoms -forming hexagons - arranged in giant layers -weak intermolecular forces between layers + allowing the layers to slide over each other = soft material
delocalised electrons
electrons that are no longer associate with any particle -can move around freely
How does graphite conduct electricity
-as only 3 of its electrons are covalently bonded, 1 electron from each atoms is free -so the delocalised electrons carry electrical charge + they move towards the positive terminal in the battery
What happens to graphite when it conducts thermal energy?
• causes the delocalised electrons to move around quicker along the layers of the graphite • energy is being transferred
Why can diamond not conduct electricity?
• as all 4 of its atoms’ electrons are being used up - it has no delocalised electrons to carry charge
allotropes
different forms of the same element