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Chapter 14 reactions
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Total cards: 13•Content version: v3•Public deck•Updated: 8/1/2026
Card preview (13)
#1
Front (Question)
Alkene to epoxide
Back (Answer)
peroxyacid epoxidation, MCPBA

#2
Front (Question)
ether to 2alkyl halides
Back (Answer)
Cleavage of ether by excess H-X

#3
Front (Question)
Alkene to ether
Back (Answer)
Alkoxymercuration HgOAc2, R-OH, NaBH4

#4
Front (Question)
Alcohol to ether
Back (Answer)
Williamson-ether synthesis, Na+, R-X or R-OTs

#5
Front (Question)
epoxide to alkoxy alcohol
Back (Answer)
Acid catalyzed opening of epoxide using ROH

#6
Front (Question)
Alkene to Halohydrin to epoxide
Back (Answer)
Cylization of Halohydrin, Br2 +H2O to form halohydrin, then strong base to form epoxide.

#7
Front (Question)
Alcohol to alkoxide
Back (Answer)
Na+ metal
#8
Front (Question)
Synthesis of sulfide
Back (Answer)
Thiolate ion as nucleophile in williamson ether synthesis
#9
Front (Question)
acid catalyzed epoxy-opening using HX
Back (Answer)

#10
Front (Question)
Acid catalyzed opening in water
Back (Answer)

#11
Front (Question)
epoxide opening with organometallics
Back (Answer)

#12
Front (Question)
base catalyzed opening with alkoxide
Back (Answer)

#13
Front (Question)
base promoted cyclization of halohydrins
Back (Answer)
