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Chapter 14 reactions

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Total cards: 13•Content version: v3•Public deck•Updated: 8/1/2026

Card preview (13)

#1
Front (Question)

Alkene to epoxide

Back (Answer)

peroxyacid epoxidation, MCPBA

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#2
Front (Question)

ether to 2alkyl halides

Back (Answer)

Cleavage of ether by excess H-X

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#3
Front (Question)

Alkene to ether

Back (Answer)

Alkoxymercuration HgOAc2, R-OH, NaBH4

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#4
Front (Question)

Alcohol to ether

Back (Answer)

Williamson-ether synthesis, Na+, R-X or R-OTs

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#5
Front (Question)

epoxide to alkoxy alcohol

Back (Answer)

Acid catalyzed opening of epoxide using ROH

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#6
Front (Question)

Alkene to Halohydrin to epoxide

Back (Answer)

Cylization of Halohydrin, Br2 +H2O to form halohydrin, then strong base to form epoxide.

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#7
Front (Question)

Alcohol to alkoxide

Back (Answer)

Na+ metal

#8
Front (Question)

Synthesis of sulfide

Back (Answer)

Thiolate ion as nucleophile in williamson ether synthesis

#9
Front (Question)

acid catalyzed epoxy-opening using HX

Back (Answer)

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#10
Front (Question)

Acid catalyzed opening in water

Back (Answer)

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#11
Front (Question)

epoxide opening with organometallics

Back (Answer)

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#12
Front (Question)

base catalyzed opening with alkoxide

Back (Answer)

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#13
Front (Question)

base promoted cyclization of halohydrins

Back (Answer)

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