3.7, 3.8, 3.9, 3.10
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what are the allotropes of carbon
diamond, graphite, silicon dioxide (silica), fullerene, graphene
how can artificial diamonds be made?
by heating pure carbon to very high temperatures under enormous pressures
Explain why the alloy of copper and zinc is harder than pure copper
• atoms are different sizes • so the layers are distorted • so the layers cannot easily slide
what happens when electrons leave the outer shell in metallic bonding
• the remaining atoms become positively charged metal ions • the delocalised electrons form a sea of electrons that moves freely between the positive metal ions
what type of attraction do metallic bonds have
strong electrostatic attraction between the positive metal ions and the sea of delocalised electrons. this means they have high melting and boiling points
do giant covalent structures have high or low melting points
they are solids at room temperature with high melting points
why are most metals malleable
atoms are arranged in layers which can slide over each other when force is applied
what are the properties of alloys that make them more useful than metals
• stronger and harder • resistant to corrosion or extreme temperatures
why can metals conduct electricity
• metals consist of giant structures • within the metal lattice, atoms lose their outer electrons • those that no longer belong to any specific metal atom are delocalised • delocalised electrons are able to move through the structure and carry a charge
describe the structure of a diamont
• each carbon atoms bonds with four other carbons, forming a tetrahedron • all covalent bonds are identical, very strong and there are no intermolecular forces
why does diamond not conduct electricity
• all outer shell electrons in carbon are held in the four covalent bonds around each carbon atom • there are no freely moving particles to carry a charge
why does diamond have a very high melting point
• diamond has a giant covalent structure • there are strong covalent bonds between the carbon atoms • these need lots of energy to break
why is the fact that diamond is hard and dense useful
it can be used in cutting tools like drills
describe the structure of graphite
• each carbon atom is able to form 3 covalent bonds to other carbon atoms forming layers of hexagons, leaving one free electron per carbon atom • free electrons along the layers are free to move and carry charge • covalent bonds between the layers are strong, but the layers are attracted to each other by weak intermolecular forces
why does graphite have a high melting point
• giant covalent structure • strong covalent bonds between carbon atoms • need lots of energy to break
why is graphite slippery
• arranged in layers • weak intermolecular forces between layers • as a result the layers can slide over each other
what is graphite used for
• pencils and industrial lubricant (because it’s slippery) • inert electrodes for electrolysis
describe the structure of graphene
• a single layer of graphite (a sheet of carbon atoms covalently bonded forming a continuous hexagonal layer) • only 1 atom thick
what are the properties of graphene
• extremely strong and very light • conducts heat and electricity • transparent • flexible
why is graphene strong
due to its unbroken pattern and the strong covalent bonds between the carbon atoms
why is graphene flexible
the strong bonds between graphene’s carbon atoms are very flexible. they can be twisted, pulled and curved to a certain extent without breaking
why is graphene transparent and what could be its use in the future
• only absorbs very small amount of visible light that hits it, which means you can see through it • gives it the potential to be used for making computer screens in the future
what are fullerenes
• a group of carbon allotropes which consist of molecules that form hollow tubes or spheres • molecules are made of interlocking hexagonal rings, but they can also be rings of five or seven carbon atoms
what are the uses of fullerenes
• can be used to trap other molecules by forming around the target molecule and capturing it, making them useful for targeted drug delivery systems • huge surface area: are useful for trapping catalyst molecules onto their surfaces making them easily accessible to the reactants • some are excellent lubricants