Module 5: Enthalpoy And Entropy
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Definitions What is enthalpy of formation
Enthalpy change when one mole of a substance is formed from its elements in their standard state
Definitions What type of energy change is enthalpy of formation
Exothermic for most
Definitions Equation for enthalpy of formation for sodium oxide
2Na(s) + 1/2 O2(g) —> Na2O(s)
Definitions What is enthalpy of combustion
Enthalpy change when one mole of a substance undergoes complete combustion with all substances in their standard states
Definitions What type of energy change is enthalpy of combustion
Exothermic
Definitions What is the equation for combustion of ethane
C2H6 + 7/2 O2 —> 2 CO2 + 3 H2O
Definitions What is enthalpy of neutralisation
Enthalpy change when one mole of water is formed in a reaction between an acid and alkali under standard conditions
Definitions What energy change is enthalpy of neutralisation
Exothermic usually -57
Definitions Equation for enthalpy of neutralisation for sulfuric acid and sodium hydroxide
1/2 H2SO4 (aq) + NaOH (aq) —> 1/2 H2SO4 (aq) + H2O (l)
Definitions What is the first ionisation energy
Enthalpy Chang when one mole of gaseous atoms loses one mole of electrons to form one mole of gaseous 1- ions
Definitions What type of reaction is first ionisation energy
Endothermic
Definitions Equation for first ionisation energy of magnesium
Mg(g) —> Mg+ (g) + e-
Definitions What is second ionisation energy
Enthalpy can change when one mole of gaseous 1+ ions loses one. Ole of electrons to form one mole of gaseous 2+ ions loses
Definitions What energy change is second ionisationnnenegry
Endothermic
Definitions Equation for second ionisation energy for magnesium
Mg+(g) —> Mg2+ (g) + e-
Definitions What is the first electron affinity
Enthalpy change when one mole of gaseous atoms gains one mole of electrons to form one mol of 1- ions
Definitions What type of energy change is first electron affinity
Exothermic for many non metals
Definitions Equations for first electron affinity of oxygen
O(g) + e- —> O-(g)
Definitions What is second electron affinity
Enthalpy Change when one mole of gaseosus 1– ions gains one mole of electrons to form one mole of gaseous 2- ions
Definitions What type of energy change is second electron affinity and why
Endothermic as adding negative electrons to a negative ion so some repulsion
Definitions Equation for second electron affinity of oxygen
O- (g) + e- —> O2- (g)
Definitions What is enthalpy of atomisation
Enthalpy change when one mole of gaseous atoms is produced from an element in its standard state
Definitions What type of energy change is enthalpy of atomisation
Endothermic
Definitions Equation for enthalpy of atomisation of iodine
1/2 I2 (s) —> I (g)