Elastomers
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What are the two types of elastomers?
• Polyether • Addition silicones
What is meant by elastic behaviour for impression materials?
• When removing IM from contact with tooth after it has set • IM has to stretch and flares out at sides to overcome bulbous aspect of tooth • Ideally it recovers to original dimension, replicating shape of tooth • Assumes perfectly elastic
How are elastomers formed?
• Formed by polymerisation with cross-linking of polymer chains • Polymerisation may produce by-products like water or hydrogen which affect dimensional stability and cast compatibility
What does the cross-linking generate?
• Elastic properties • Causes fluid to solid transition
What 3 mechanical properties of elastomers affect the accuracy by which the surface features are recorded?
• Surface details (reproduction) • Flow/viscosity • Contact angle/ wettability
What 3 mechanical properties affect accuracy of the dimensions and shape of final impression?
• Elastic recovery % • Stiffness (flexibility) • Tear strength
What is Shore A hardness?
• Specific hardness test for IM
What is the shark fin test?
• Relates to ability of IM to deal with undercuts
What other mechanical properties are important for Elastomers?
• Shore A hardness • Shark fin test (flow under P) • Setting shrinkage • Dimensional stability • Thermal expansion coefficient • Biocompatibility
What is VIRTUAL?
• An addition polyvinylsiloxane • Made by IVPCLAR-VIVADENT
What are the important properties of VIRTUAL?
• Has good hydrophillic properties during impression taking ( good for fine detail of oral hard and soft tissues) • Good compatibility with moist dentin and gingival tissue • Exhibit very low contact angles with excellent wettability • Excellent moisture displacement • Colour contrast gives margins that are easy to read • Precise impressions • High tear strength • Hardness adjusted to clinical needs • Good elastic recovery
What is Viscosity?
• Measure of materials ability to flow • Determines a materials potential for making close contact with hard/soft tissue surface so how well it records fine detail • Range can be low, medium or high
What does the contact angle indicate?
• How readily ‘wet’ the tooth surface is and how closely the IM envelops the tooth surface • Low contact angle means large % of its vol make contact with target surface = no space between globules of IM = ideal • Large contact angle = spaces between globules of IM = some surface not replicated
What are hydrophilic silicones?
• Non ionic surfactant • Incorporated into addition silicones as they have difficulty making good contact with moist tooth surface • They wet tooth surface
What is the ISO 4823?
• International standard measure for surface reproduction of IM • Measures how accurately surface is represented • Test involves placing IM along surface which has grooves of 20, 50 and 75um • Uniform pressure applied across width of IM • An IM that record the 20um grooves gives most accurate surface detail
Are Impression material truly elastic?
• No they are all Visco-elastic to some extent • When load applied IM will gradually reach strain required • When load released strain gradually drops • Does not return to original dimension and experiences permanent deformation (aka permanent strain)
What is definition of Viscoelastic behaviour?
• Occurs when, after being stretched or compressed, a material fails to return to its original dimensions/shape and there is permanent deformation
How is viscoelastic behaviour influenced by tray removal method?
• If load time is less and impression tray removed with sharp pull then less overall permanent strain (lower deformation)
When does the IM elasticity begin to develop?
• IM ability to flow diminishes • Only when setting reaction progressed to certain extent does materials elasticity begin to develop fully • Even when IM firm to touch it is still developing elasticity • Wait a few mins before removing it
What is the shark fin test?
• Used to record an undercut • Undercut can only be recorded when IM reaches the narrow zone (between the gingivae and tooth surface) • IM inserted into cylindrical chamber that has slot of specified depth and forced down (pressure applied)
What does large fin length and short fin length mean on shark fin test?
• Large fin length means high flow and will flow readily into sulcus and undercuts • Short fin length has low flow
What is the tear strength?
• Stress material will withstand before fracturing
What is rigidity?
• stress/strain ratio • Stress needed to cause material to change shape
What is an example of Polyether elastomer?
• Impregum Penta soft (medium)