Redox, Group 2 + 7
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What is oxidation?
Loss of electrons Gain of oxygen Loss of hydrogen
What is reduction?
Gain of electrons Loss of oxygen Gain of hydrogen
What is a disproportionation reaction?
When a species is simultaneously oxidised and reduced
Which element has the highest boiling point in period 3 and why?
Silicon because it’s giant covalent
What elements other than silicon have high melting and boiling points in period 3 and why?
Sodium, magnesium and aluminium because they all have metallic bonds
Which element has the lowest melting and boiling point in period 3 and why?
Argon because it’s monatomic with very weak Van der Waals forces between atoms
What is the trend in atomic radius down group 2 and why?
As you go down the group the atomic radius increases because there are more electron shells
What is the trend in first ionisation energy as you go down group 2 and why?
As you go down the group the first ionisation energy decreases because shielding increases, therefore there’s weaker attraction from the nucleus to the electron in its outer shell
What is the trend in melting point as you go down group 2 and why?
As you go down the group the melting point decreases because as the ions become larger, the strength of the metallic bond decreases
What is the equation for a group 2 metal reacting with cold water?
X + 2H2O –> X(OH)2 + H2
What is the equation for magnesium reacting with steam?
Mg + H2O –> MgO + H2
What is the trend in reactivity going down group 2 and why?
As you go down the group, reactivity increases because there is increased shielding and less attraction between the nucleus and outer electron
What will you observe when magnesium reacts with water?
It will react slowly with cold water
What will you observe when magnesium reacts with steam?
A bright white light and a white precipitate forming
What will you observe when calcium reacts with water?
Bubbles and fizzes White precipitate forms
What will you observe when strontium / barium react with water?
Bubbles and fizzes Forms a colourless solution
What is the trend in reactivity with water going down group 2?
It increases
What is the trend in solubility of group 2 hydroxides as you go down the group?
It increases
What is produced when calcium hydroxide reacts with water?
Lime water
What is the trend in the solubility of group 2 sulphates as you go down the group?
It decreases
Which group 2 sulphates are completely insoluble?
Strontium sulphate and barium sulphate
What are some uses of magnesium hydroxide?
Antiacid for indigestion relief Laxative
What is a use of calcium hydroxide?
To reduce acidity of soils so more crops can be grown
What are some uses of barium sulphate?
Absorbing X rays Aiding the investigation of problems in digestive and bowel systems