Periodicity
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What are the elements sat between the dividing line between metals and non-metals called? What properties do they have?
Metalloids, a combination of metal and non-metal properties
What is the trend of atomic radius down a group?
Increase in principle energy levels, therefore increase in shielding, outer electron is further from the nucleus.
What is the trend of atomic radius across a period?
Decreases as number of protons (nuclear charge) increases, shielding stays constant, electrons are more strongly attracted to the nucleus and atomic radius decreases.
What does periodicity mean?
• Repeating trends of physical or chemical properties
What is ionisation?
Involves the loss of an electron to form a positive ion
Give the definition of the First Ionisation Energy
• The energy required to remove of 1 mol of electrons from 1 mol of gaseous atoms
What is the trend of the 1st IE down a group?
Decreases, electron is removed from a higher principle energy level, electron is further from the nucleus, more shielding, weaker attraction between nucleus and outer electron
What is the trend of the 1st IE across a period?
Increases, number of protons increase, shielding is constant/ atomic radius decreases, stronger attraction between nucleus and outer electron.
What are the two anomalies of the general trend of the 1st IE across period 3? Explain why.
Al and S Al - IE decreases, electron is removed from a higher energy p sub-level, weaker attraction between nucleus and outer electron S - IE decreases, pair of electrons in a p-orbital, extra repulsion means less energy required to remove outer electron
Explain successive ionisation energies and explain what they can be used for
• Will always increase, positive charge on ion increases, ionic radius decreases, nuclear attraction on the outer electron increases • Can be used to find an element’s group number (look for the big jump) • The big jump happens when an electron has been removed from a principle energy level that is much closer to the nucleus
Give the definition of metallic bonding
Strong electrostatic force of attraction between positive ions and delocalised electrons
Why does a lattice form in metallic bonding?
• Positive ions repel • Sea of electrons attracted to positive ions
Give the 3 factors that determine the strength of metallic bonding
• Ionic charge on metal - stronger=stronger bond • Number of delocalised electrons - more electrons donated to sea the stronger metallic bond • Atomic radius - smaller=stronger
What are the 3 properties of metals?
• Good conductors of electricity and heat as delocalised electrons are free to move • Very high m.p and b.p as they have a strong attraction between positive ions and delocalised electrons • Malleable and ductile (can be hammered into shape) - Layers of ions that can slide over each other
Give the bonding and structure of the Period 2 elements
• Lithium and Beryllium - metallic bonding - forms a metallic lattice • Carbon - covalent bonding to form giant covalent substance; diamond, graphite or graphene - high m.p and b.p, strong covalent bonds require a lot of energy to break • N2, O2, F2, Ne - non polar molecules, covalent bonding. All have weak London forces
Describe the 3 giant covalent substances that carbon forms
• Diamond - each carbon atom bonded to four other carbon atoms, no delocalised electrons • Graphite - each carbon atom bonded to three other carbon atoms, forming hexagonal layers. Weak London forces between layers, delocalised electrons • Graphene - 1 layer of graphite, delocalised electrons
Give the bonding and structure of period 3 elements
• Na, Mg, Al - metallic bonding - metallic lattice • Si, giant covalent substance. Each silicon atom bonded to 4 other silicon atoms. Strong covalent bonds require a lot of energy to break. No delocalised electrons • P4, S8, Cl2, Ar - All non polar, weak London forces require little energy to break
Explain what melting point is
• Some of the attractive forces between the particles are broken. Now move more freely around each other but are still close together • The stronger the forces, the more difficult it is to melt
Explain what boiling point is
• All the attractive forces between the particles are broken. Free to move more randomly