Chapter 14

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Total cards: 24•Content version: v4•Public deck•Updated: 8/1/2026

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Front (Question)

Where is the H-NMR signal for benzene?

Back (Answer)

single unspilt signal at 7.27

Front (Question)

What is a Phenol?

Back (Answer)

Benzene with an OH

Front (Question)

What is Benzyl?

Back (Answer)

A Benzene-CH2-R

Front (Question)

What is Benzoyl?

Back (Answer)

Benzene attached to a carbonyl group

Front (Question)

How do you name benzene rings with single substituents?

Back (Answer)

substituent + benzene Chlorobenzene, NitroBenzene

Front (Question)

How do you name benzene rings with multiple substituents using the number method?

Back (Answer)

(1,3-blahblahsuffixbenzene)The highest ranked functional group becomes the suffix.

Front (Question)

How do you name benzene rings with multiple substituents using the Ortho-Meta-Para system?

Back (Answer)

Highest priority is one, Ortho is 2,6. Meta is 3, 5. Para is 4. Use the prefix o-, m-, or p-.

Front (Question)

What is Anisole?

Back (Answer)

Benzene-OCH3

Front (Question)

What is a Nitro Group?

Back (Answer)

NO2

#10

Front (Question)

What is Toluene?

Back (Answer)

Benzene-CH3

#11

Front (Question)

What is Sulfonic?

Back (Answer)

SO3H

#12

Front (Question)

What is Aceto?

Back (Answer)

Carbonyl bonded to CH3

#13

Front (Question)

What is an Aniline?

Back (Answer)

Benzene ring-NH2

#14

Front (Question)

What is Xylene?

Back (Answer)

Benzene with two methyls

#15

Front (Question)

What is an -oic suffix?

Back (Answer)

Carboxylic acid functional group

#16

Front (Question)

What is sec/neo/iso/tert?

Back (Answer)

All carbons except one form a continuous chain- iso All carbons except two form a continuous chain- Neo A functional group is attached to a secondary carbon-sec A functional group is attached to a tertiary carbon-tert

#17

Front (Question)

What is the nomenclature for aldehydes?

Back (Answer)

Suffix al (or aldehyde for common names. If -CHO is attached to a ring, use -carbaldehyde as suffix. Carbon of carbonyl is always one.

#18

Front (Question)

What is the nomenclature for Ketones?

Back (Answer)

Prefix Oxo, suffix one. Common name is substituent groups alphabetically + ketone

#19

Front (Question)

What is Huckel’s rule?

Back (Answer)

Cyclically conjugated compounds having 4n+2 electronic are aromatic. Cyclically conjugated compounds having 4n electrons are anti aromatic. Compounds with neither of these are nonaromatic

#20

Front (Question)

How does Huckel’s rule apply to negative charges?

Back (Answer)

Negative charges count as two pi electrons.

#21

Front (Question)

How does Huckel’s rule apply to positive charges?

Back (Answer)

Positive charges do not have any pi electrons, but can participate in resonance

#22

Front (Question)

How does Huckel’s rule apply to atoms in the cyclic molecule?

Back (Answer)

If an atom has one or two lone pairs and does not already have a double bond attached to it, it counts as two pi electrons

#23

Front (Question)

What does cyclic conjugation mean?

Back (Answer)

All atoms can participate in resonance structure.

#24

Front (Question)

What are the differing properties in Antiaromatic / Nonaromatic / Aromatic compounds?

Back (Answer)

Aromatic compounds are very stable and thus have low reactivity. Antiaromatic compounds are very unstable and thus have high reactivity..