3.3.5 - alcohols
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what is the general formula for the alcohol homologous series
Cn, H2n+1, OH
what is the suffix for alcohols
-ol
do you need numbers for naming alcohols
yes - which carbon atom the alcohol functional group is attached to
what is the suffix for 2 -OH groups
-diol
what is the suffix for 3 -OH groups
-triol
primary alcohols
• OH group is attached to a carbon with one alkyl group attached
secondary alcohols
• OH group is attached to a carbon with 2 alkyl groups attached
tertiary alcohols
• OH group is attached to a carbon with 3 alkyl groups attached
dehydration of alcohols
you can make alkenes by eliminating water from alcohols in a dehydration reaction (i.e. elimination of water)
what does dehydration of alcohols allow you to produce and why is this important
allows you to produce alkenes from renewable resources which is important as you can produces polymers e.g. polyethene without needing oil
in the dehydration of ethanol, what is ethanol heated with
ethanol is heated with a concentrated sulfuric acid catalyst
dehydration of an alcohol: step 1
• lone pair of electrons from the oxygen bonds to an H+ from the acid. The alcohol is protonated, giving the oxygen a positive charge
dehydration of an alcohol: step 2
• positively charged oxygen pulls electrons away from the carbon. An H20 molecule leaves, creating an unstable carbocation intermediate
dehydration of an alcohol: step 3
• carbocation loses an H+
dehydration of an alcohol: step 4
• alkene is formed along with H2O and H+
what can also be used as a catalyst in the dehydration of alcohols
phosphoric acid
give 2 ways ethanol can be produced?
• hydration of ethene • fermentation of glucose
what is the standard industrial method for producing alcohols
hydrate an alkene using steam in the presence of an acid catalyst
how to produce ethanol from ethene
steam hydration of ethene is used industrially to produce ethanol
conditions for hydration of ethene to make ethanol
ethene can be hydrated by steam at 300 degrees C and a pressure of 60atm. it needs a solid phosphoric(V) acid catalyst
is the reaction to make ethanol from ethene reversible?
yes it is reversible
hydration of ethene: step 1
• pair of electrons from the double bond bonds to an H+ from the acid
hydration of ethene: step 2
• lone pair of electrons from a water molecule bonds to the carbocation
hydration of ethene: step 3
water loses an H+