1.12 Acids and Bases
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Define a Bronstead-Lowry acid
A proton donor
Define a Bronstead-Lowry base
Proton acceptor
What ion causes a solution to be acidic ?
• H+ (hydrogen ion) • H3O+ (Oxonium ion).
What ion causes a solution to be alkaline ?
Hydroxide ion (OH-)
Write an equation for the ionisation of water
• 2H2O (l) ⇌ H3O+ (aq) + OH- (aq) • H2O (l) ⇌ H+ (aq) + OH- (aq).
Derive Kw using the formula for the ionisation of water
• Kc = [H+][OH-] / [H2O] • Kc [H2O] = [H+][OH-] • [H2O] is so large that it can be assumed that it is constant • Therefore Kw = [H+][OH-].
What is the value of Kw at 298K
1.0 x 10 ⁻¹⁴
What physical factors affect the value of Kw? How do they affect it?
• Only temperature effects the value of Kw • If temperature increases, the equilibrium moves to the right • Kw increases therefore and the pH of pure water increases.
Why is pure water still neutral, even if pH does not equal 7 ?
[H+] = [OH-]
Give an expression for pH in terms of H+
pH = -log([H+])
What is the relationship between pH and concentration of H+?
Lower pH = higher concentration of H+.
By what scale does the concentration of H+ increase if you jump from pH 2 to 1 ?
x10.
How do you find the [H+] from pH ?
[H+] = 10 ⁻ᵖᴴ
How do you find [OH-] from pH ? (298K)
• Find [H+] • Use Kw / [H+] = [OH-].
What is different when finding the concentration of H+ in diprotic and triprotic acids ?
You need to multiply the concentration of the acid by the number of protons to find [H+].
How do you calculate the pH of a strong alkaline solution ?
• Use Kw to calculate [H+] from [OH-] • Use pH = -log([H+])
Define the term strong acid
One which fully dissociates into water : XH -> X- + H+.
Define the term strong base
One which fully dissociates into water: XOH -> X+ + OH-
What is the difference between a concentrated acid and strong acid ?
• Concentrated means many moles per dm3 • Strong refers to amount of dissociation.
What are weak acids and bases ?
Acids / bases which only partially dissociate into their ions in a solution.
Give some examples of strong acids
HCl, H2SO4, HNO3, H3PO4
Give some examples of strong bases
NaOH, CaCO3, Na2CO3
Give an example of a weak acid
CH3COOH, any organic acid.
Give an example of a weak base
NH3