Periodicity QP
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Give an equation for phosphorus oxide with water. Suggest a pH. [2]
[1] P4O10 + 6H2O → 4H3PO [2] 1
Explain, in terms of crystal structure and bonding, why silicon oxide has a higher melting point then phosphorus oxide [4]
[1] SiO2 is macromolecular [2] Strong covalent bonds [3] P4O10 is molecular or simple covalent molecule [4] Weak van der Waals forces between molecules
Give one element which deviates from the general trend of ionisation energy and why? [3]
[1] Aluminium [2] (Outer) electron in (3)p orbital / sub-shell [3] (3p) higher in energy / slightly more shielded (than 3s)
Meaning of periodicity [1]
[1] Repeating pattern/trends (of physical or chemical properties/reactions)
Rank the size of S, P, Cl and Ar
S8 > P4 > Cl2 > Ar
Why does Na2O form an alkaline solution when reacting with water [2]
[1] Sodium oxide contains O2– ions [2] These O2– ions react with water forming OH– ions
Ionic equation when P4O10 react with an excess NaOH [1]
[1] P4O10 + 12OH– -> 4PO43- + 6H2O