Group 2
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Group 2
Earth alkali metals
Properties (gp2)
Shiny when freshly cut Tarnish upon exposure to O2 Soft (harder down group) Low density (increases down gp) Electrical conductors
Appearance of gp2 metals
Shiny when freshly cut Tarnish when exposed to o2 as reactive so forms thin oxide layer
Softness (gp2)
Softness increases going down Weaker metallic bond due to increase in shielding
First ionisation energy going down (gp2)
More shells so atomic radius increases going down More shielding experienced So easier to lose electron going down
Metallic bonding
Electrostatic attraction between positive metal ions and negative delocalised electron
Melting point and boiling point (gp2)
Decreases down group Larger atomic size distance between positive metal ions and delocalised electrons increases Lower charge density Weaker metallic bonding
Reaction w water equation
X(s) + 2H2O(l) -> X(OH)2(aq) +H2 (g)
Reaction w steam equation
X(s) + H2O(g) ~> XO(s) + H2
Trend in reactivity in water (gp2)
Reactivity Increases going down As atomic size increases So larger atomic radius Weaker metallic attraction between positive ion and delocalised electron
Beryllium w water liquid
Little to no reaction
Beryllium w steam
Vigorous heating or reaction w steam produces white solid (beryllium oxide) h2 gas bubbles
Mg w cold water
Slow reaction White ppt Colourless gas bubbles (h2)
Mg w steam
Burns w white flame Produces white solid (MgO) H2 gas bubbles
Calcium w water
Reacts vigorously Produces white solid that dissolves in water to form clear colourless limewater Ca(OH)2 H2 gas bubbles
Calcium w steam
Vigorous reaction Bright flame White solid CaO H2 bubbles
Using Mg q
MgSO4 test
Prepare sample solution Add few drops of Barium Hydroxide Positive test = white ppt forms Because barium Sulfate is insoluble in water
Test for sulfate ions
Reagent: barium chloride Adding few drops of HCL Adding few drops of BaCl2 Positive test: white ppt of barium sulfate forms
Group2 + HCl
Reacts vigorously
Ca + H2SO4
Reactions slowed stopping H bubbles from rising
Group 2 metals
Group 2 sulfate become sulfates become less soluble down group
Barium sulfate use
Insoluble So used for x ray imaging to view digestive system to show outline of organs