Percentage composition and empirical formula
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What is empirical formula?
• Empirical formula is the simplest whole number ratio of each type of atom of a compound.
What is the molecular and empirical formula of glucose, methanoic acid, and ethanoic acid?
• Glucose:C6H12O6 = CH2O • Methanoic acid: HCOOH (or CH2O2) = CH2O2 • Ethanoic acid: CH3COOH (or C2H4O2) = C2H4O2
Empirical Formula Calculation
• Write down the mass of each element. • Look up the relative atomic mass of each element. • Work out how many Moles are of each element (divide by Ar) • Choose the element present in the smallest amount. • Divide the moles of each of the other elements in the compound by the moles of the one in the smallest amount.
Percentage mass Eq.
= total mass of element in the compound (x100)/total mass of compound

Calculating empirical formula from percentage composition by mass
• Mass of each element in 100 grams acid. • Relative atomic mass of each element. • Convert to moles of each element. • Identify the element present in the smallest amount. • Divided by the smallest.