energetics 3.1.4 in all papers
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enthalpy change what is an enthalpy change?
• the heat energy change measured under constant pressure. • its measured in J/KJ per moles.
enthalpy change what does standard enthalpy change refer to?
• standard conditions, 100kpa, 25 degrees/ 298 kelvins.
enthalpy change what is an endothermic reaction?
• a reaction where heat energy is transferred from the surrondings to the reactants, tempreture decreases.
enthalpy change what is an exothermic reaction?
• a reaction where heat energy is released to the surrondings.
enthalpy change what is bond breaking?
• the input of energy, making it endothermic (+).
enthalpy change how do you work out enthalpy change?
• mass of water (g) x change in tempreture of water x specific heat capacity of water (KJ). • assuming that all energy from the burning fuel is transferred to the water. • density g of water is 1gcm-3, so 24.5cm3 g of water = 24.5 g
enthalpy change what is bond making?
• the output of energy, making it exothermic (-).
enthalpy change what is standard enthalpy of combustion?
• the enthalpy change when 1 mole of a substance is completely burnt in excess oxygen with all reactants being in their standard state under standard conditions.
bond enthalpy define mean bond enthalpy.
• the energy required to break 1 mole of a covalent bond averaged across many compounds containing the bond.
bond enthalpy which type of bonds are stronger?
• shorter the covalent bond, the stronger the bond. • triple bonds are generally shorter than double or single bonds, so more energy is required to break them resulting in a positive bond enthalpy.
what is the enthalpy change of formation?
• when one mole of a substance is formed from its constituent elements under standard conditions, all reactants and products being in their standard states.
how do you work out enthalpy change of formation?
enthalpy change = sum of the enthalpy change of formation of products - sum of the enthalpy change of reactants.
hess’s law what is hess’s law?
• states that the enthalpy change during a reaction is independent of the route taken, providing the initial and final conitions are the same. • (the sum of the indirect route = direct route)
hess’s law why might you not get a 1 mole of methane in a mixture of carbon and hydrogen?
• carbon is highly unreactive. • a range of other hydrocarbons could form, meaning we wont get 1 mole of methane.
what are 2 disadvantages of using a glass beaker on tripod and gauze?
• glass is a poorer conductor than copper • tripod and gauze would reduce heat transfer
why would the concentration of a solution not be able to be determined using calorimetry?
its colourless