Unit 2
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Bonds
Atoms bond in order to reach a stable 8 valence state
Ionic Bond
Electrostatic forces held together ions. Generally between metals and nonmetals
Metallic Bond
Bons between metals that are neither covalent or ionic: the e- is delocalized so they are free to roam - like a soup
Covalent Bond
Sharing electrons and forming a molecule generally non-metal and non-metal
Lattice
structure of a molecule
Network covalent bonds
Lattice of covalent bonds making a 3D structure
What are some characteristics of Ionic Bonds (3)
• Strong lattice structure • Solid at room temp • High melting and boiling points
What are some factors for melting points? (2)
• Greater charge = greater melting point • Smaller size = greater melting point
What are some factors for bond energies? (3)
• Greater charge = greater bond energy • Smaller size = greater bond energy • More bonds = higher energy (Greater bond order)
What are some characteristics of metallic bonds? (2)
• malleable and ductile • they can form alloys
Alloy
combination of elements where at least one is a metal
What are the two types of Alloys and explain
• Interstitial alloy - different radii sizes • subsitual alloy - similar radii sizes
What are some characteristics of Network Covalent structures? (2)
• Hard • High melting and boiling points
Aqueous
a substance put in H2O
Bond Order:
(total # of bonds)/(# of atoms)
What are the three rules to keep in mind when you draw Lewis Dot Structures?
• Least Electronegative = central atom • Add extra e- till valence shells are finished • Add extra e- to central atom
What is the maximum amount of e- the central atom can have?
No more than 12 They can take up to 12 due to the d-block
Resonance Forms
A bond can go anywhere - in reality, the e- is at all of those locations the equal amount of time
Incomplete Octets (2)
• B and Al - stable with 6 e- • H - stable with 2 e-
Expanded octets
there can be up to 12 e- ONLY AND ONLY IF n = 3 NEVER n = 2 n = 1
Formal Charge
(# of valence e-) - (# of valence e- assigned) PER ATOM
How do I know if an atom is stable?
If the formal charge per atom is 0 or close to 0
VSEPR
Valence electron model that predicts the three dimensional geometry of the molecule
For formal charge, a lone pair stands for
2 e-