Atomic Structure
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what is an atom
• the smallest part of an element • invisible, but broken down into many different subatomic particles • made up of protons, neutron and electrons
What is an isoptope?
Same number of protons; different number of neutrons
what is the electromagnetic spectrum
electromagnetic waves can travel through space + depending on wavelength, through matter.
Formula for wavelength speed
c= y x v v= frequency y= wavelength c= velocity of travel (speed)
what is the emission spectra ( EXICTED STATE TO GROUND STATE; GIVING OUT ENERGY)
Line Spectrum: when energy is supplied to individual elements they emit a spectrum which only contains emissions at particular wavelengths. Each element has its own characteristic spectrum, known as a line spectrum (not continuous) • each element emits specific wavelengths • each wavelength corresponds to a discrete amount of energy
How does the emission spectra work?
• can be used to identify particular elements, as each element has its own, unique emission spectra • energy supplied to electrons= electrons become energy and becoming EXCITED (move from ground state to excited state) • When electrons drop from a higher level to a lower level they emit energy • energy corresponds to a particular wavelength and shows up as a line in the spectrum • when electrons return to ground state, the lines occur in the ultraviolet region
Electronic Configuration
electorns found in orbitals, each orbital can contain a maximum of 2 electrons each with opposite spins
THE AUFBAU principle:
The orbitals with the lowest energy are filled first each orbital can contain a maximum of two electrons HUNDS RULE: orbitals within the same subshell are filled singly first
Exeptions to aufbau prinicple
CHROMIUM: [Ar] 4s1 3d5 COPPER: [Ar] 4s1 3d10 IRON: [Ar] 3d6
SHAPES OF ORIBTALS
S» SPHERICAL P» DUNG BELLS, 3 TYPES: PX (cross) PY AND PZ(sideways) (vertical)
emmision spectra for: • hot object • hot gas
HOT OBJECT: continous spectra (all the frequencies of light) Hot Gas: certain little lines (certain frequencies OF LIGHT) discontinous spectra
what is the absorbtion spectra
-absorbtion of energy -from ground state to excited state emmision +aborbtion =complete spectra
what is BOHRS explanation of the hydrogen spectra
• positive proton in nucleus • electrons moving around it • each orbit has a definitive energy associated with Citi
what is the ground state
electrons in their lowest energy level; with energy it can move to its excited state (other levels)
what are chemical properties of an element determined by
the electronic configuration
how can a scientists determine that electrons have distinct levels through which they travel from their ground-> excited state
emission spectra consist of discrete lines representing transients between the levels; if electors could be anywhere he spectra would be continuous; the convergence of lines in the spectra show that successive levels get closer in energy